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SL Paper 1

What are possible names of a molecule with molecular formula C4H10O?

        I.     1-Methoxypropane

        II.     2-Methylpropan-2-ol

        III.     Butanal

A.     I and II only

B.     I and III only

C.     II and III only

D.     I, II and III




What is the order of increasing boiling point?

A.     C4H10 < CH3COOH < CH3CH2CHO < CH3CH2CH2OH

B.     C4H10 < CH3CH2CHO < CH3CH2CH2OH < CH3COOH

C.     CH3COOH < CH3CH2CH2OH< CH3CH2CHO < C4H10

D.     C4H10 < CH3CH2CH2OH < CH3CH2CHO < CH3COOH




Which alcohols are oxidized by acidified potassium dichromate(VI) solution when heated?

A. I and II only 

B. I and III only 

C. II and III only 

D. I, II and III




Which monomer is used to form the polymer with the following repeating unit?

A. CH3CH=CHCH

B. CH3CH2CH=CH

C. CH3CH2CH2CH

D. (CH3)2C=CH2




Which of these reactions proceeds by a free radical mechanism in the presence of UV light?

A.     C6H6 + Cl2 → C6H5Cl + HCl

B.     C6H6 + 3H2 → C6H12

C.     CH2CH2 + HBr → CH3CH2Br

D.     CH3CH3 + Cl2 → CH3CH2Cl + HCl




What is the mechanism for the reaction of propene with iodine in the dark?

A.     electrophilic addition

B.     electrophilic substitution

C.     free radical substitution

D.     nucleophilic substitution




Which reagents and conditions are best for converting propan-1-ol into propanoic acid?

A.  Reflux with acidified potassium dichromate (VI)

B.  Reflux with aqueous sodium hydroxide

C.  Distil with acidified potassium dichromate (VI)

D.  Distil with aqueous sodium hydroxide




Which compounds belong to the same homologous series?

A.     CHCCH2CH3, CHCCH2CH2CH3

B.     CH3CH2CH2CH2OH, CH3CH2OCH2CH3

C.     CH2CHCH3, CH3CH2CH2CH3

D.     CH3COCH3, CH3CH2OCH3




Which functional groups are present in serine?

A.  nitro, carbonyl and carboxyl

B.  amino, hydroxyl and carbonyl

C.  nitro, carboxyl and hydroxyl

D.  amino, carboxyl and hydroxyl




What is produced when chlorobutane is treated with aqueous sodium hydroxide solution?

A.  butane

B.  butanoic acid

C.  butanal

D.  butan-1-ol




Which reaction mechanisms are typical for alcohols and halogenoalkanes?




How many dichlorinated butane isomers can be formed by the halogenation of CH3CH2CH2CH3 with excess Cl2 in the presence of UV light?

A.  4

B.  6

C.  8

D.  10




Which describes the reaction between a halogen and ethane?




What type of reaction occurs when C6H13Br becomes C6H13OH?

A.  Nucleophilic substitution

B.  Electrophilic substitution

C.  Radical substitution

D.  Addition




What is the name of this compound, using IUPAC rules?

M18/4/CHEMI/SPM/ENG/TZ2/25

A.     1,1-dimethylpropanoic acid

B.     3,3-dimethylpropanoic acid

C.     2-methylbutanoic acid

D.     3-methylbutanoic acid




What is the name of the compound with this molecular structure applying IUPAC rules?

A.     1-methylpropanoic acid

B.     2-methylpropanoic acid

C.     2-methylbutanoic acid

D.     3-methylbutanoic acid




What is the IUPAC name of the following molecule?

A. 2-bromo-3-ethylbutane

B. 3-methyl-4-bromopentane

C. 2-ethyl-3-bromobutane

D. 2-bromo-3-methylpentane




Which functional group is surrounded in the molecule?

A. hydroxyl

B. carboxyl

C. carbonyl

D. ether




Which structure represents a repeating unit of a polymer formed from propene?

A.  –CH2–CH(CH3)–

B.  –CH2–CH2–CH2

C.  –CH(CH3)–CH(CH3)–

D.  –CH2–CH2




Which compound has the lowest boiling point?

A. CH3CH2CH2CH2CH2CH3

B. CH3CH2CH2CH2CH3

C. CH3CH(CH3)CH2CH3

D. CH3C(CH3)2CH3




What is the mechanism of the reaction between alkenes and halogens in the absence of light?

A. radical substitution

B. electrophilic substitution

C. electrophilic addition

D. nucleophilic substitution




Which type of reaction occurs when methanol and propanoic acid react together in the presence of a catalyst?

A. Addition

B. Condensation

C. Redox

D. Neutralization 




Which type of reaction occurs between an alcohol and a carboxylic acid?

A. Addition

B. Oxidation

C. Esterification

D. Polymerization




Which molecule has a tertiary nitrogen?

A.     (CH3)2NH

B.     (C2H5)4N+I

C.     C3H7N(CH3)2

D.     C6H5NH2




Which compound could be formed when CH3CH2CH2OH is heated with acidified potassium dichromate(VI)?

        I.     CH3CH2CHO

        II.     CH3CH2COOH

        III.     CH3COCH3

A.     I and II only

B.     I and III only

C.     II and III only

D.     I, II and III




What is the major product of the reaction between HCl and but-2-ene?

A. 1,2-dichlorobutane

B. 2,3-dichlorobutane

C. 1-chlorobutane

D. 2-chlorobutane




How many structural isomers of C6H14 exist?

A. 4

B. 5

C. 6

D. 7




What is the general formula of alkynes?


A.  CnH2n+2

B.  CnH2n

C.  CnH2n−2

D.  CnHn




Which series is in order of increasing boiling point?

A.  CH2CH2CH3OH    CH3COCH3         CH3CH2CH3

B.  CH3CH2CH3         CH3COCH3          CH2CH2CH3OH

C.  CH3COCH3          CH2CH2CH3OH    CH3CH2CH3

D.  CH3CH2CH3         CH2CH2CH3OH    CH3COCH3




Which conditions are used to convert ethanol to ethanal?

A.     Excess oxidizing agent and reflux

B.     Excess oxidizing agent and distillation

C.     Excess ethanol and reflux

D.     Excess ethanol and distillation




The structure of a drug used to treat symptoms of Alzheimer’s disease is shown below. Which functional groups are present in this molecule?

A. Hydroxyl and ester 

B. Hydroxide and ether 

C. Hydroxyl and ether 

D. Hydroxide and ester




Which compound cannot undergo addition polymerization?




Which alcohol would produce a carboxylic acid when heated with acidified potassium dichromate(VI)?

A. propan-2-ol

B. butan-1-ol

C. 2-methylpropan-2-ol

D. pentan-3-ol




Which compounds react to form CH3CH2CH2COOCH(CH3)2?

 

A.   propanoic acid and propan-2-ol

B.   propanoic acid and butan-2-ol

C.   butanoic acid and propan-1-ol

D.   butanoic acid and propan-2-ol




Which is correct for benzene?

 

A.   It readily undergoes addition reactions and decolourises bromine water.

B.   It contains alternate single and double carbon–carbon bonds and is planar.

C.   Its 1H NMR spectrum shows six signals and it readily undergoes substitution reactions.

D.   Its 1H NMR spectrum shows one signal and it forms a single C6H5Br isomer.




Which compounds cause the colour of acidified potassium manganate(VII) solution to change from purple to colourless?

I.    CH3CH2CH2CH2OH

II.   (CH3)3CCH2OH

III.  CH3CH2CH(OH)CH3

 

A.   I and II only

B.   I and III only

C.   II and III only

D.   I, II and III




Which of the following can be both formed from bromoethane and converted directly into ethanal?

CH3CH2Br → X
X → CH3CHO

A. CH3CH2OH

B. CH3OCH3

C. CH3COOH

D. H2C=CHBr




Methane reacts with chlorine in sunlight.

CH4 (g) + Cl2 (g) → CH3Cl (g) + HCl (g)

Which type of reaction occurs?

A. free-radical substitution

B. electrophilic substitution

C. nucleophilic substitution

D. electrophilic addition




Which functional group is present in paracetamol?

A.     Carboxyl

B.     Amino

C.     Nitrile

D.     Hydroxyl




What is the name of this compound, applying IUPAC rules?

A.  4-methylhex-2-ene

B.  4-ethylpent-2-ene

C.  2-ethylpent-3-ene

D.  3-methylhex-4-ene




Which compound can be oxidized when heated with an acidified solution of potassium dichromate(VI)?

A. CH3C(O)CH2CH3

B. CH3CH2CH(OH)CH3

C. (CH3)3COH

D. CH3(CH2)2COOH




Which compound contains a secondary carbon atom?

A.     CH3CH(Cl)CH(CH3)2

B.     (CH3)2CHCH2Cl

C.     (CH3)3CCl

D.     CH3CH2Cl




What is the IUPAC name of the molecule shown?

A.  2,4-dimethylhexane

B.  3,5-dimethylhexane

C.  2-methyl-4-ethylpentane

D.  2-ethyl-4-methylpentane




What is the product of the reaction between hex-3-ene and steam?

A.     Hexan-1-ol

B.     Hexan-2-ol

C.     Hexan-3-ol

D.     Hexan-4-ol




Which compound is not in the same homologous series as the others?

A.  C5H12

B.  C6H12

C.  C7H16

D.  C8H18




Which is a homologous series?

A.  C2H4, C3H5, C4H6

B.  C2H2, C3H4, C4H6

C.  C2H2, C2H4, C2H6

D.  C2H2, C4H4, C6H6




Which is a propagation step in the free-radical substitution mechanism of ethane with chlorine?

A.  Cl2 → 2 •Cl

B.  •C2H5 + Cl2 → C2H5Cl + •Cl

C.  •C2H5 + •Cl → C2H5Cl

D.  C2H6 + •Cl → C2H5Cl + •H




Which are structural isomers?

       I.     CH3CH2OH and CH3OCH3

       II.     HOCH2CH3 and CH3CH2OH

       III.     CH3COOH and HCOOCH3

A.     I and II only

B.     I and III only

C.     II and III only

D.     I, II and III




What is the name of this substance using IUPAC rules?

A.  2-ethyl-1-methylbutan-1-ol

B.  1-methyl-2-ethylbutan-1-ol

C.  3-ethylpentan-2-ol

D.  3-ethylpentan-4-ol




Which monomer would produce the polymer shown?

A.  CF3CCl2F

B.  CF3CClHF

C.  CF2CClF

D.  CF2CF2




What is the IUPAC name of this molecule?

A.  1,1,2,4-tetramethylpent-1-ene

B.  2,4,5-trimethylhex-4-ene

C.  2,4,5,5-tetramethylpent-4-ene

D.  2,3,5-trimethylhex-2-ene




Which is in the same homologous series as CH3OCH3?

A.  CH3COCH3

B.  CH3COOCH3

C.  CH3CH2CH2OH

D.  CH3CH2CH2OCH3




Which monomer forms the polymer shown?

A.  CH(Cl)=CH(CH3)

B.  CH2=C(Cl)CH3

C.  (CH3)2CHCl

D.  CH2=CHCl




Which spectra would show the difference between propan-2-ol, CH3CH(OH)CH3, and propanal, CH3CH2CHO?

I.   mass
II.  infrared
III. 1H NMR

A.  I and II only

B.  I and III only

C.  II and III only

D.  I, II and III




What are the functional groups in the aspirin molecule?

I. Ether II. Carboxyl III. Ester

A.     I and II only

B.     I and III only

C.     II and III only

D.     I, II and III




What is the order of increasing boiling point for the isomers of C5H12?

 

A.   CH3CH2CH2CH2CH3 < CH3CH(CH3)CH2CH3 < CH3C(CH3)3

B.   CH3C(CH3)3 < CH3CH(CH3)CH2CH3 < CH3CH2CH2CH2CH3

C.   CH3C(CH3)3 < CH3CH2CH2CH2CH3 < CH3CH(CH3)CH2CH3

D.   CH3CH(CH3)CH2CH3 < CH3C(CH3)3 < CH3CH2CH2CH2CH3




What is the name of this compound, using IUPAC rules?

A. 3-methylbutan-3-ol

B. 2-ethylpropan-2-ol

C. 2-methylbutan-2-ol

D. 3-methylbutan-2-ol




Which will react with a halogen by an electrophilic substitution mechanism?




Which pair of compounds are structural isomers?


A.  Propane and propene

B.  Propanal and propanone

C.  Propan-1-ol and propanal

D.  Propyl propanoate and propanoic acid




Which combination best describes what is happening to chloromethane, CH3Cl, in the equation below?

CH3Cl (g) + H2 (g) CH4 (g) + HCl (g)

A.  Oxidation and addition

B.  Oxidation and substitution

C.  Reduction and addition

D.  Reduction and substitution




Which compounds are members of the same homologous series?

A.  propanal, propanone, propanoic acid

B.  propane, propene, propyne

C.  hexan-1-ol, hexan-2-ol, hexan-3-ol

D.  ethanol, propan-1-ol, butan-1-ol




What is formed in a propagation step of the substitution reaction between bromine and ethane?

A.  CH3CH2

B.  CH3CH2CH2CH3

C.  H•

D.  Br




Which mechanism does benzene most readily undergo?

A.  Nucleophilic substitution

B.  Electrophilic substitution

C.  Electrophilic addition

D.  Free radical substitution




Which functional groups are present in this molecule?

A.  carbonyl, ether, nitrile

B.  carbonyl, ester, nitrile

C.  carboxyl, ether, amine

D.  carboxyl, ester, amine




Which molecule will decolorize bromine water in the dark?

A.  cyclohexane

B.  hexane

C.  hex-1-ene

D.  hexan-1-ol