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	<title>DP Chemistry: Alkanes, alkenes & addition polymers</title>
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  <meta name="description" content="The naming, structural isomerism and physical properties of the alkanes and alkenes have all been covered in the previous sub-topic. This sub-topic is concerned with the chemical reactions of the alkanes and the alkenes. Despite the fact that their main use is as fuels the alkanes are remarkably unreactive chemically (their old name was the paraffins which means ‘little activity’). The lack of reactivity of alkanes...">
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science </a></li><li><a href="../19519/metals-and-icp-spectroscopy-1.html">Metals and ICP spectroscopy</a></li><li><a href="../19541/catalysts--1.html">Catalysts </a></li><li><a href="../19580/liquid-crystals-1.html">Liquid crystals</a></li><li><a href="../19665/polymers--1.html">Polymers  </a></li><li><a href="../19672/nanotechnology-1.html">Nanotechnology</a></li><li><a href="../19843/environmental-impact-plastics-1.html">Environmental impact - plastics</a></li><li><a href="../19858/superconducting-metals-x-ray-crystallography--1.html">Superconducting metals & X-ray crystallography </a></li><li><a href="../19666/condensation-polymers-1.html">Condensation polymers</a></li><li><a href="../19916/environmental-impact-heavy-metals-1.html">Environmental impact - heavy metals</a></li></ul></li><li><a href="../19284/option-b--1.html" class="father">Option B </a><ul class="level-2"><li><a href="../19290/introduction-to-biochemistry--1.html">Introduction to biochemistry  </a></li><li><a href="../19287/proteins-enzymes--1.html">Proteins & enzymes </a></li><li><a href="../19291/lipids-1.html">Lipids</a></li><li><a href="../19299/carbohydrates--1.html">Carbohydrates </a></li><li><a href="../19305/vitamins--1.html">Vitamins   </a></li><li><a href="../19313/biochemistry-the-environment--1.html">Biochemistry & the environment </a></li><li><a href="../19336/proteins-enzymes-ahl--1.html">Proteins & enzymes (AHL)   </a></li><li><a href="../19347/nucleic-acids--1.html">Nucleic acids   </a></li><li><a href="../19361/biological-pigments--1.html">Biological pigments   </a></li><li><a href="../19366/stereochemistry-in-biomolecules-1.html">Stereochemistry in biomolecules</a></li></ul></li><li><a href="../19390/option-c--1.html" class="father">Option C </a><ul class="level-2"><li><a href="../19391/energy-sources-1.html">Energy sources</a></li><li><a href="../19407/fossil-fuels-1.html">Fossil fuels</a></li><li><a href="../19411/nuclear-fusion-nuclear-fission-reactions-1.html">Nuclear fusion & nuclear fission reactions</a></li><li><a href="../19429/solar-energy-1.html">Solar energy</a></li><li><a href="../19437/environmental-impact-global-warming-1.html">Environmental impact - global warming</a></li><li><a href="../19453/electrochemistry-rechargeable-batteries-fuel-cells-1.html">Electrochemistry, rechargeable batteries & fuel cells</a></li><li><a href="../19458/nuclear-fusion-fission-hl--1.html">Nuclear fusion & fission (HL)    </a></li><li><a href="../19470/photovoltaic-cells-and-dsscs-1.html">Photovoltaic cells and DSSCs</a></li></ul></li><li><a href="../19078/option-d-1.html" class="father">Option D</a><ul class="level-2"><li><a href="../19079/pharmaceutical-products-drug-action--1.html">Pharmaceutical products & drug action </a></li><li><a href="../19158/aspirin-penicillin--1.html">Aspirin & penicillin  </a></li><li><a href="../19174/opiates-1.html">Opiates</a></li><li><a href="../19184/ph-regulation-of-the-stomach-1.html">pH regulation of the stomach</a></li><li><a href="../19194/antiviral-medications--1.html">Antiviral medications </a></li><li><a href="../19211/environmental-impact-of-some-medications-1.html">Environmental impact of some medications</a></li><li><a href="../19254/taxol-a-chiral-auxiliary-case-study-1.html">Taxol - a chiral auxiliary case study</a></li><li><a href="../19258/nuclear-medicine--1.html">Nuclear medicine  </a></li><li><a href="../19273/drug-detection-analysis--1.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../16592/practical-scheme-of-work-ia--1.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../16682/internal-assessment-1.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../18892/scaffolding-the-investigation-1.html">&#039;Scaffolding&#039; the investigation</a></li><li><a href="../18896/timing-organisation--1.html">Timing & organisation </a></li><li><a href="../18905/choosing-the-research-question-1.html">Choosing the research question</a></li><li><a href="../18946/personal-engagement-1.html">Personal engagement</a></li><li><a href="../18950/exploration-1.html">Exploration</a></li><li><a href="../18957/analysis-1.html">Analysis</a></li><li><a href="../18965/evaluation-1.html">Evaluation</a></li><li><a href="../18966/communication-1.html">Communication</a></li><li><a href="../19882/internal-standardization-of-the-ia-1.html">Internal standardization of the IA</a></li><li><a href="../19901/submitting-the-samples-for-moderation-2.html">Submitting the samples for moderation</a></li><li><a href="../33754/ten-suggestions-for-ias-using-secondary-data-1.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../37544/gaining-full-marks-for-a-databased-ia--1.html">Gaining full marks for a databased IA </a></li><li><a href="../19506/ia-example-marking-exercise--1.html">IA example & marking exercise </a></li><li><a href="../23929/genuine-examples-of-moderated-ia-reports-1.html">Genuine examples of moderated IA reports</a></li><li><a href="../25234/examples-of-teacher-marked-ia-reports--1.html">Examples of teacher-marked IA reports </a></li><li><a href="../37542/history-of-internal-assessment-1.html">History of Internal Assessment</a></li></ul></li><li><a href="../16598/mandatory-laboratory-components-1.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../16613/formula-of-magnesium-oxide--1.html">Formula of magnesium oxide </a></li><li><a href="../16612/determining-the-mr-of-an-unknown-gas-1.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../16615/acid-base-titrations--1.html">Acid-base titrations </a></li><li><a href="../16616/a-green-acid-base-practical-1.html">A green acid-base practical</a></li><li><a href="../16617/analysis-of-aspirin-tablets-1.html">Analysis of aspirin tablets</a></li><li><a href="../16618/caco3-in-egg-shells-1.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../16644/enthalpy-changes-1.html">Enthalpy changes</a></li><li><a href="../16631/reaction-rates-1.html">Reaction rates</a></li><li><a href="../16635/rate-dependent-factors-1.html">Rate-dependent factors</a></li><li><a href="../16636/determining-ea-for-a-reaction-1.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../16637/iodination-of-propanone-1.html">Iodination of propanone</a></li><li><a href="../18144/titrations-with-a-ph-meter-1.html">Titrations with a pH meter</a></li><li><a href="../18355/redox-titration-with-kmno4--1.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../16640/voltaic-cells-1.html">Voltaic cells</a></li><li><a href="../16659/3-d-molecular-modelling--1.html">3-D molecular modelling </a></li></ul></li><li><a href="../17168/other-good-practicals-1.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../17196/common-chemical-reactions-1.html">Common chemical reactions</a></li><li><a href="../227/elements-oxides-of-the-third-period--1.html">Elements & oxides of the third period </a></li><li><a href="../17239/the-halogens-1.html">The halogens</a></li><li><a href="../17162/boiling-points-of-mixtures-1.html">Boiling points of mixtures</a></li><li><a href="../17170/polarity-of-molecules-1.html">Polarity of molecules</a></li><li><a href="../18083/le-chateliers-principle--1.html">Le Chatelier&#039;s principle </a></li><li><a href="../19582/determining-kc-for-an-esterification-reaction-1.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../18164/redox-reactions-of-vanadium--1.html">Redox reactions of vanadium </a></li><li><a href="../18351/chlorine-in-swimming-pools--1.html">Chlorine in swimming pools </a></li><li><a href="../18178/analysis-of-cuii-ions-in-solution--1.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../18179/percentage-of-copper-in-brass-1.html">Percentage of copper in brass</a></li><li><a href="../18356/electrolytic-cells--1.html">Electrolytic cells </a></li><li><a href="../18598/reactions-of-organic-compounds-1.html">Reactions of organic compounds</a></li><li><a href="../18752/hydrolysis-of-halogenoalkanes-1.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../18784/preparation-of-13-dinitrobenzene--1.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../19022/determination-of-an-organic-structure-1.html">Determination of an organic structure</a></li><li><a href="../19887/preparation-of-nylon-66-1.html">Preparation of nylon 6,6</a></li><li><a href="../19343/determination-of-vitamin-c-content--1.html">Determination of vitamin C content </a></li><li><a href="../19342/hydrolysis-of-starch--1.html">Hydrolysis of starch </a></li><li><a href="../19159/preparation-purification-of-aspirin--1.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../18851/ict-in-practical-work-1.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../18852/data-logging--1.html">Data logging </a></li><li><a href="../18853/software-for-graph-plotting--1.html">Software for graph plotting </a></li><li><a href="../18854/spreadsheets-for-data-processing--1.html">Spreadsheets for data processing </a></li><li><a href="../18855/databases-1.html">Databases</a></li><li><a href="../18856/computer-modelling-simulations--1.html">Computer modelling & simulations </a></li></ul></li><li><a href="../16594/group-4-project-1.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../16595/practicalities-1.html">Practicalities</a></li><li><a href="../16596/reflective-statement--2.html">Reflective statement </a></li></ul></li><li><a href="../16666/a-new-laboratory-1.html">A new laboratory?</a></li></ul></li><li><a href="../16284/exams-1.html">Exams</a><ul class="level-1"><li><a href="../16286/essential-facts-1.html" class="father">Essential Facts</a><ul class="level-2"><li><a href="../16287/objectives-command-terms-1.html">Objectives & command terms</a></li><li><a href="../16288/grade-descriptors-1.html">Grade descriptors</a></li><li><a href="../16289/grade-boundaries-1.html">Grade boundaries</a></li></ul></li><li><a href="../16302/paper-1-multiple-choice-1.html" class="father">Paper 1 (Multiple Choice)</a><ul class="level-2"><li><a href="../16303/advice-to-students-paper-1-1.html">Advice to students (Paper 1)</a></li><li><a href="../31515/practice-paper-1-exams-1.html">Practice Paper 1 exams</a></li></ul></li><li><a href="../16305/paper-2-1.html" class="father">Paper 2</a><ul class="level-2"><li><a href="../16306/advice-to-students-paper-2-1.html">Advice to students (Paper 2)</a></li><li><a href="../16307/areas-of-difficulty-1.html">Areas of difficulty</a></li></ul></li><li><a href="../16313/paper-3--1.html" class="father">Paper 3 </a><ul class="level-2"><li><a href="../16314/advice-to-students-paper-3-1.html">Advice to students (Paper 3)</a></li><li><a href="../16342/data-response-questions-1.html">Data response questions</a></li><li><a href="../20054/experimental-work-questions-1.html">Experimental work questions</a></li></ul></li><li><a href="../16324/the-examination-process-1.html" class="father">The examination process</a><ul class="level-2"><li><a href="../16316/setting-the-exam-papers-1.html">Setting the exam papers</a></li><li><a href="../16317/predicted-grades-1.html">Predicted grades</a></li><li><a href="../16318/marking-the-papers-1.html">Marking the papers</a></li><li><a href="../16319/commenting-on-the-exams-1.html">Commenting on the exams</a></li><li><a href="../16320/grade-awarding-1.html">Grade Awarding</a></li><li><a href="../16321/enquiry-upon-results-1.html">Enquiry upon results</a></li><li><a href="../16322/chief-examiners-report-1.html">Chief Examiner&#039;s report</a></li><li><a href="../16323/retaking-the-exam-1.html">Retaking the exam</a></li></ul></li><li><a href="../16325/faqs-1.html">FAQs</a></li></ul></li><li><a href="../3147/ib-core-1.html">IB Core</a><ul class="level-1"><li><a href="../3149/learner-profile-1.html">Learner Profile</a></li><li><a href="../21735/extended-essays--1.html" class="father">Extended Essays </a><ul class="level-2"><li><a href="../21736/overview--1.html">Overview </a></li><li><a href="../21780/responsibilities-1.html">Responsibilities</a></li><li><a href="../21790/resources-1.html">Resources</a></li><li><a href="../21800/research-1.html">Research</a></li><li><a href="../21804/writing-the-essay-1.html">Writing the essay</a></li><li><a href="../21810/assessment-1.html">Assessment</a></li><li><a href="../22434/summary-of-advice--1.html">Summary of advice </a></li><li><a href="../25272/faqs--1.html">FAQs </a></li></ul></li><li><a href="../307/theory-of-knowledge-tok-1.html" class="father">Theory of Knowledge (TOK)</a><ul class="level-2"><li><a href="../41171/the-12-tok-concepts-1.html">The 12 TOK concepts</a></li><li><a href="../3507/why-tok-chemistry-1.html">Why TOK & Chemistry?</a></li><li><a href="../3505/a-modern-paradigm-1.html">A modern paradigm</a></li></ul></li></ul></li><li><a href="../17783/fast-track-to-tests-questions-1.html">Fast track to tests & questions</a><ul class="level-1"><li><a href="../17784/sl-multiple-choice-tests-on-individual-topics-1.html">SL Multiple choice tests on individual topics</a></li><li><a href="../24351/sl-multiple-choice-quizzes-on-sub-topics-1.html">SL Multiple choice &#039;quizzes&#039; on sub-topics</a></li><li><a href="../31519/sl-practice-paper-1-exams-1.html">SL Practice Paper 1 exams</a></li><li><a href="../17786/sl-questions-on-each-sub-topic-1.html">SL Questions on each sub-topic</a></li><li><a href="../20431/sl-paper-3-section-a-questions-1.html">SL Paper 3 Section A questions</a></li><li><a href="../17792/sl-questions-on-the-options-1.html">SL Questions on the options</a></li><li><a href="../24897/sl-quizzes-on-option-sub-topics--1.html">SL Quizzes on option sub-topics </a></li><li><a href="../17785/hl-multiple-choice-tests-on-individual-topics-1.html">HL Multiple choice tests on individual topics</a></li><li><a href="../24352/hl-multiple-choice-quizzes-on-sub-topics-1.html">HL Multiple choice &#039;quizzes&#039; on sub-topics</a></li><li><a href="../31520/hl-practice-paper-1-exams--1.html">HL Practice Paper 1 exams </a></li><li><a href="../17787/hl-questions-on-each-sub-topic--1.html">HL Questions on each sub-topic </a></li><li><a href="../20428/hl-paper-3-section-a-questions-1.html">HL Paper 3 Section A questions</a></li><li><a href="../17793/hl-questions-on-the-options-1.html">HL Questions on the options</a></li><li><a href="../24973/hl-quizzes-on-option-sub-topics-1.html">HL Quizzes on option sub-topics</a></li><li><a href="../41573/printable-versions-of-written-tasks--1.html">Printable versions of written tasks </a></li></ul></li><li><a 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title="MC test: Theories of acids & bases">MC test: Theories of acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40963/theories-of-acids-bases-questions-1.html" title="Theories of acids & bases questions">Theories of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18126/properties-of-acids-bases-1.html" title="Properties of acids & bases">Properties of acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24663/mc-test-properties-of-acids-bases--1.html" title="MC test: Properties of acids & bases ">MC test: Properties of acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40964/properties-of-acids-bases-questions-1.html" title="Properties of acids & bases questions">Properties of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18140/ph-scale-1.html" title="pH scale">pH scale</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24668/mc-test-the-ph-scale-1.html" title="MC test: The pH scale">MC test: The pH scale</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40971/ph-scale-questions-1.html" title="pH scale questions">pH scale questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18152/strong-weak-acids-bases-1.html" title="Strong & weak acids & bases">Strong & weak acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24670/mc-test-strong-weak-acids-bases-1.html" title="MC test: Strong & weak acids & bases">MC test: Strong & weak acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40972/strong-weak-acid-bases-questions-1.html" title="Strong & weak acid & bases questions">Strong & weak acid & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18156/acid-deposition-1.html" title="Acid deposition">Acid deposition</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24674/mc-test-acid-deposition-1.html" title="MC test: Acid deposition">MC test: Acid deposition</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40983/acid-deposition-questions-1.html" title="Acid deposition questions">Acid deposition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18160/lewis-acids-bases-1.html" title="Lewis acids & bases">Lewis acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24710/mc-test-lewis-acids-bases-1.html" title="MC test: Lewis acids & bases">MC test: Lewis acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40986/lewis-acids-bases-questions-1.html" title="Lewis acids & bases questions">Lewis acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18250/acid-base-calculations-1.html" title="Acid base calculations">Acid base calculations</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24714/mc-test-calculations-involving-acids-bases--1.html" title="MC test: Calculations involving acids & bases ">MC test: Calculations involving acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40988/acid-base-calculations-questions--1.html" title="Acid-base calculations questions ">Acid-base calculations questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../26161/ph-titration-curves-1.html" title="pH titration curves">pH titration curves</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../26158/mc-test-ph-curves-1.html" title="MC test: pH curves">MC test: pH curves</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41000/ph-curves-questions--1.html" title="pH curves questions ">pH curves questions </a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18350/topics-9-19-1.html" title="Topics 9 & 19">Topics 9 & 19</a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18365/oxidation-reduction-1.html" title="Oxidation & reduction">Oxidation & reduction</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24725/mc-test-oxidation-reduction-1.html" title="MC test: Oxidation & reduction">MC test: Oxidation & reduction</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41033/oxidation-reduction-questions-1--1.html" title="Oxidation & reduction questions (1) ">Oxidation & reduction questions (1) </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41034/oxidation-reduction-questions-2-1.html" title="Oxidation & reduction questions (2)">Oxidation & reduction questions (2)</a></li><li class="" style="padding-left: 42px"><i class="expander 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title="Electrochemical cells (AHL) ">Electrochemical cells (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24742/mc-test-electrochemical-cells-ahl-1.html" title="MC test: Electrochemical cells (AHL)">MC test: Electrochemical cells (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41098/electrochemical-cells-1-ahl-questions-1.html" title="Electrochemical cells (1) (AHL) questions">Electrochemical cells (1) (AHL) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41099/electrochemical-cells-2-ahl-questions-1.html" title="Electrochemical cells (2) (AHL) questions">Electrochemical cells (2) (AHL) questions</a></li></ul></ul><li class="ancestor parent" style="padding-left: 14px"><i class="expander fa fa-caret-right fa-rotate-90"></i><a href="../18475/topics-10-20--1.html" title="Topics 10 & 20 ">Topics 10 & 20 </a></li><ul class="level-2 expanded"><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18497/fundamentals-of-organic-chemistry--1.html" title="Fundamentals of organic chemistry ">Fundamentals of organic chemistry </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24749/mc-test-fundamentals-of-organic-chemistry-1.html" title="MC test: Fundamentals of organic chemistry">MC test: Fundamentals of organic chemistry</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41111/fundamentals-of-organic-chemistry-1-questions-1.html" title="Fundamentals of organic chemistry (1) questions">Fundamentals of organic chemistry (1) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41112/fundamentals-of-organic-chemistry-2-questions-1.html" title="Fundamentals of organic chemistry (2) questions">Fundamentals of organic chemistry (2) questions</a></li></ul><li class="current parent" style="padding-left: 28px"><i class="expander fa fa-caret-right fa-rotate-90"></i><a href="alkanes-alkenes-addition-polymers-1.html" title="Alkanes, alkenes & addition polymers">Alkanes, alkenes & addition polymers</a></li><ul class="level-3 expanded"><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24750/mc-test-alkanes-alkenes-addition-polymers-1.html" title="MC test: Alkanes, alkenes & addition polymers">MC test: Alkanes, alkenes & addition polymers</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41121/alkanes-questions-1.html" title="Alkanes questions">Alkanes questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41124/alkenes-questions-1.html" title="Alkenes questions">Alkenes questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18741/alcohols--1.html" title="Alcohols ">Alcohols </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24772/mc-test-alcohols-1.html" title="MC test: Alcohols">MC test: Alcohols</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41125/alcohols-questions-1.html" title="Alcohols questions">Alcohols questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18742/halogenoalkanes-benzene--1.html" title="Halogenoalkanes & benzene ">Halogenoalkanes & benzene </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24797/mc-test-halogenoalkanes-benzene-1.html" title="MC test: Halogenoalkanes & benzene">MC test: Halogenoalkanes & benzene</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41130/halogenoalkanes-benzene-questions-1.html" title="Halogenoalkanes & benzene questions">Halogenoalkanes & benzene questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18762/nucleophilic-substitution--1.html" title="Nucleophilic substitution ">Nucleophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24757/mc-test-nucleophilic-substitution-1.html" title="MC test: Nucleophilic substitution">MC test: Nucleophilic substitution</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41138/nucleophilic-substitution-questions-1.html" title="Nucleophilic substitution questions">Nucleophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18766/electrophilic-addition--1.html" title="Electrophilic addition ">Electrophilic addition </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24805/mc-test-electrophilic-addition-electrophilic-substitution-reacti-2.html" title="MC test: Electrophilic addition & electrophilic substitution reactions">MC test: Electrophilic addition & electrophilic substitution reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41148/electrophilic-addition-questions-1.html" title="Electrophilic addition questions">Electrophilic addition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18780/electrophilic-substitution--2.html" title="Electrophilic substitution ">Electrophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41149/electrophilic-substitution-questions-1.html" title="Electrophilic substitution questions">Electrophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18793/reduction-reactions--1.html" title="Reduction reactions ">Reduction reactions </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24811/mc-test-reduction-reactions-1.html" title="MC test: Reduction reactions">MC test: Reduction reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41150/reduction-reactions-questions-1.html" title="Reduction reactions questions">Reduction reactions questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18797/synthetic-routes--1.html" title="Synthetic routes ">Synthetic routes </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24822/mc-test-synthetic-routes-1.html" title="MC test: Synthetic routes">MC test: Synthetic routes</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41152/synthetic-routes-questions--1.html" title="Synthetic routes questions ">Synthetic routes questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18844/stereoisomerism--1.html" title="Stereoisomerism  ">Stereoisomerism  </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24817/mc-test-stereoisomerism-1.html" title="MC test: Stereoisomerism">MC test: Stereoisomerism</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41166/stereoisomerism-questions-1.html" title="Stereoisomerism questions">Stereoisomerism questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17285/topics-11-21--1.html" title="Topics 11 & 21 ">Topics 11 & 21 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17276/uncertainty-errors--1.html" title="Uncertainty & errors ">Uncertainty & errors </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24818/mc-test-uncertainties-errors-1.html" title="MC test: Uncertainties & errors">MC test: Uncertainties & errors</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../38869/uncertainty-error-questions--1.html" title="Uncertainty & error questions ">Uncertainty & error questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../15014/graphical-techniques-1.html" title="Graphical techniques">Graphical techniques</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24819/mc-test-graphical-techniques-1.html" title="MC test: Graphical techniques">MC test: Graphical techniques</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39387/graphical-techniques-questions--1.html" title="Graphical techniques questions ">Graphical techniques questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18968/spectroscopic-identification-of-organic-compounds-1.html" title="Spectroscopic identification of organic compounds">Spectroscopic identification of organic compounds</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24820/mc-test-spectroscopic-identification-of-organic-compounds--1.html" title="MC test: Spectroscopic identification of organic compounds ">MC test: Spectroscopic identification of organic compounds </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39388/index-of-hydrogen-deficiency-questions-1.html" title="Index of hydrogen deficiency questions">Index of hydrogen deficiency questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39351/identification-from-spectra-question-1-1.html" title="Identification from spectra - Question 1">Identification from spectra - Question 1</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39353/identification-from-spectra-question-2-1.html" title="Identification from spectra - Question 2">Identification from spectra - Question 2</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39354/identification-from-spectra-question-3-1.html" title="Identification from spectra - Question 3">Identification from spectra - Question 3</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39355/identification-from-spectra-question-4-1.html" title="Identification from spectra - Question 4">Identification from spectra - Question 4</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39356/identification-from-spectra-question-5-1.html" title="Identification from spectra - Question 5">Identification from spectra - Question 5</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39357/identification-from-spectra-question-6-1.html" title="Identification from spectra - Question 6">Identification from spectra - Question 6</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39358/identification-from-spectra-question-7-1.html" title="Identification from spectra - Question 7">Identification from spectra - Question 7</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39359/identification-from-spectra-question-8-1.html" title="Identification from spectra - Question 8">Identification from spectra - Question 8</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39360/identification-from-spectra-question-9-1.html" title="Identification from spectra - Question 9">Identification from spectra - Question 9</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39361/identification-from-spectra-question-10-1.html" title="Identification from spectra - Question 10">Identification from spectra - Question 10</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19027/spectroscopic-identification-of-organic-compounds-ahl--1.html" title="Spectroscopic identification of organic compounds (AHL) ">Spectroscopic identification of organic compounds (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24821/mc-test-spectroscopic-identification-of-organic-compounds-ahl-1.html" title="MC test: Spectroscopic identification of organic compounds (AHL)">MC test: Spectroscopic identification of organic compounds (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39375/identification-from-spectra-question-11-1.html" title="Identification from spectra - Question 11">Identification from spectra - Question 11</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39376/identification-from-spectra-question-12-1.html" title="Identification from spectra - Question 12">Identification from spectra - Question 12</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39377/identification-from-spectra-question-13-1.html" title="Identification from spectra - Question 13">Identification from spectra - Question 13</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39378/identification-from-spectra-question-14-1.html" title="Identification from spectra - Question 14">Identification from spectra - Question 14</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39379/identification-from-spectra-question-15-1.html" title="Identification from spectra - Question 15">Identification from spectra - Question 15</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a 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</div><section id="main-content"><div id="toc-1672972933" class="toc"><a href="#" class="toc-switcher" title="Show table of contents"><small><i class="fa fa-reorder"></i> Table of contents <span class="pull-right"><i class="fa fa-chevron-down"></i></span></small></a></div><h1><img class="ico" src="../../../img/icons/standard-1.png"> <img class="ico" src="../../../img/icons/higher-1.png"> 10.2 Functional group chemistry (6.5 hours)<br><br>1. Alkanes, alkenes &amp; addition polymers (estimated 3.5 hours)</h1><div class="pinkBg"><div><h2>Pause for thought</h2><p>The naming, structural isomerism and physical properties of the alkanes and alkenes have all been covered in the <a href="chemistry/topics-10-20/introduction.htm">previous sub-topic</a>. This sub-topic is concerned with the chemical reactions of the alkanes and the alkenes. Despite the fact that their main use is as fuels the alkanes are remarkably unreactive chemically (their old name was the <em>paraffins</em> which means &lsquo;little activity&rsquo;). The lack of reactivity of alkanes is not just due to their realtively strong bond enthalpies and non-polar nature. The fact that they are virtually non-polar (due to the similar electronegativities of carbon and hydrogen and their often symmetrical shapes) does explain why they do not attract electrophiles or nucleophiles. However it is not true that just because they are relatively non-polar they should be unreactive <em>per se</em>. Many non polar molecules, e.g. oxygen, fluorine, silicon tetrachloride and boron trifluoride are extremely reactive. Equally their bond enthalpies are not that remarkably strong. Although the carbon to hydrogen bond has a relatively high value of approximately 414 kJ mol<sup>-1</sup>, the carbon-carbon single bond is in the region of 346 kJ mol<sup>-1</sup> which is about average for bond enthalpies.<br><br><img alt="" class="right noborder" height="336" src="../../../ib/chemistry/images/Core and AHL/Organic/Hydrolysis SiCl4(1).jpg" title="Unlike tetrachloromethane, silicon tetrachloride can expand its octet so reacts vigorously with water." width="355"> One of the real reasons why alkanes are so relatively unreactive is that carbon atoms are unable to &lsquo;expand their octet&rsquo; to form what is technically known as a <em>hypervalent</em> molecule. Of course carbon atoms do contain empty 3d orbitals but these are much higher in energy than the occupied 2s and 2p (or hybridized combinations of 2s and 2p) orbitals so they cannot be utilized. Contrast this with a silicon atom which has the electronic configuration 1s<sup>2</sup>2s<sup>2</sup>2p<sup>6</sup>3s<sup>2</sup>3p<sup>2</sup>. Silicon can utilize its empty d orbitals and expand its octet. This explains why tetrachloromethane, CCl<sub>4</sub>, is almost completely inert, particularly in the presence of water, whereas silicon tetrachloride, SiCl<sub>4</sub>, reacts vigorously with water.<br><br>SiCl<sub>4</sub>(l) + 2H<sub>2</sub>O(l) &rarr; SiO<sub>2</sub>(s) + 4HCl(aq)<br><br>Unlike a carbon atom, a silicon atom can act as a Lewis acid and accept a non-bonding pair of electrons from a water molecule as it expands its octet in the process (see right). The fact that carbon cannot do this is as much responsible for the inactivity of alkanes as its bond enthalpies and lack of bond polarity.</p><hr class="hidden"><p>Some books also state that because carbon is a much smaller atom relative to silicon then the water molecule cannot approach it to react. This may be true in the case of tetrachlormethane but is not really true in the case of methane where the four hydrogen atoms take up much less room than the four chlorine atoms in tetrachloromethane and yet methane, unlike silane, SiH<sub>4</sub> (which undergoes spontaneous combustion in air and decomposes above 420 <sup>o</sup>C), is still relatively unreactive.</p><hr class="hidden"><p>One of the most obvious differences between alkanes and unsaturated compounds such as alkenes is that the unsaturated compounds burn in air with a much more yellow and smoky flame.</p><p>Although this is not a definitive way to distinguish between alkanes and alkenes &ndash; bromine water in the absence of ultraviolet light does that - it is a very noticeable difference. Why should this be so?</p><p>One proposed solution would be that the alkene needs more oxygen to burn than alkanes and that as the amount of oxygen in the surrounding air is limited alkenes do not burn so completely. However a quick glance at the relevant equations will show that this is not the case. For example, one mol of ethane requires 3.5 mol of oxygen to combust completely whereas one mol of ethene requires only 3 mol of oxygen for complete combustion. According to this the ethene should burn more completely in air.</p><p>C<sub>2</sub>H<sub>6</sub>(g) + 3.5O<sub>2</sub>(g) &rarr; 2CO<sub>2</sub>(g) + 3H<sub>2</sub>O(l)</p><p>C<sub>2</sub>H<sub>4</sub>(g) + 3O<sub>2</sub>(g) &rarr; 2CO<sub>2</sub>(g) + 2H<sub>2</sub>O(l)</p><p>Perhaps it is because the C=C bond enthalpy is stronger than the C-C bond enthalpy and so it does not break so readily. If this was the case we might expect the enthalpy of combustion of ethane to be much greater than the enthalpy of combustion of ethene, particularly as more water is formed (although there are less C-H bonds to break).</p><p style="text-align: center;"><img alt="" height="225" src="../../../ib/chemistry/images/Core%20and%20AHL/Organic/Table%20for%20alkanes.jpg" width="440"></p><p>It is greater but only by about 10% per mole. In fact when 1.0 g of ethene burns in a plentiful supply of oxygen the heat given out is only slightly less than when 1.0 g of ethane completely combusts.</p><p><a href="noborder"><img alt="" src="../../../ib/chemistry/images/Core%20and%20AHL/Organic/carbide%20lamp.jpg" style="width: 277px; height: 247px; float: left;"></a><img alt="" class="noborder" src="../../../ib/chemistry/images/Core%20and%20AHL/Organic/welding.jpg" style="width: 276px; height: 389px; float: right;">Approximately the same amount of heat is also given out with 1.0 g of ethyne, C<sub>2</sub>H<sub>2</sub>(g), which requires less oxygen (2.5 mol per mol of ethyne). Ethyne burning in air used to be used to provide light in miners&rsquo; and cavers&rsquo; lamps (see left) and on early automobiles as the flame is so yellow. However when burned in oxygen the heat evolved from the very hot blue flame is used to weld metal, as in oxy acetylene welding (see right).</p><p>It seems as though the smokiness is somehow connected with the degree of unsaturation but it is not really clear why. You can demonstrate this by burning a small amount of benzene in air (<strong>you will need to actually burn methylbenzene as the use of benzene is banned</strong>). The flame is not only extremely yellow and smoky but small pieces of black soot float around in the atmosphere afterwards. An unsaturated liquid such as benzene or methylbenzene takes longer to ignite than a gas as it needs to be vaporized first. The ratio of oxygen to hydrocarbon required to combust benzene completely is much lower at 7.5:6, compared to the much higher ratio of 21:6 when burning ethane. On this basis it is perhaps surprising that benzene is so smoky when it requires so much less oxygen than ethane when it is burned in air. Another example in chemistry of where a simple observation is not so easy to explain?</p><hr class="hidden"></div></div><hr class="hidden"><div class="box"><h2>Nature of Science</h2><p>Organic chemical reactions involving functional group interconversions are among the key factors responsible for the progress made in the development and applications of scientific research.</p><hr class="hidden"></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><div class="yellowBg"><div><h2><strong>Learning outcomes</strong></h2><p>After studying this sub-topic students should be able to:</p><p><strong>Understand:</strong></p><ul><li>Alkanes have low reactivity and undergo free-radical substitution reactions.</li><li>Alkenes are more reactive than alkanes and undergo addition reactions.</li><li>Alkanes and alkenes can be distinguished by the use of bromine water.</li><li>A wide range of monomers can be used to form addition polymers. These polymers form the basis of<br>the plastics industry.</li></ul><p><strong>Apply their knowledge to:</strong></p><ul><li>Write equations for the complete and incomplete combustion of hydrocarbons.</li><li>Explain the reactions of alkanes (methane and ethane) with halogens in ultraviolet light as an example of free-radical substitution involving photochemical homolytic fission.</li><li>Write equations for the reactions of alkenes with hydrogen and halogens.</li><li>Write equations for the reactions of symmetrical alkenes with hydrogen halides and water.</li><li>Outline the addition polymerization of alkenes.</li><li>Relate the structure of a monomer to the addition polymer it forms and the repeating unit.</li></ul></div></div></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal;"></span></b></h4><div class="yellowBg"><div><h4><b><span style="font-weight: normal;"><strong>Clarification notes</strong></span></b></h4><p>The initiation, propagation and termination steps in<br>free-radical substitution reactions should be covered.<br>Free radicals should be represented by a single dot.</p><hr class="hidden"><h4>International-mindedness</h4><p>The release of methane from ruminants in countries such as New Zealand and the S. American countries of Brazil, Uruguay and Argentina makes a significant contribution to total greenhouse gas emissions.<br>Methane is also produced from landfill sites.<br>Some countries are developing the technologies to capture the methane from landfill sites as a source of energy for electricity and heat generation.</p></div></div></td></tr></tbody></table></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h2><span style=""><b><span style="font-weight: normal;"><strong>Teaching tips</strong></span></b></span></h2><p><span style=""><span style="font-weight: normal;">You have probably already covered the complete combustion of hydrocarbons when you did</span></span> <a href="../17669/topics-5-15--1.html" title="New 2014 programme (First exams 2016) » Core &amp; AHL » Teaching each topic &amp; sub-topic » Topics 5 &amp; 15 ">Topic 5: Energetics/thermochemistry</a><span style=""><span style="font-weight: normal;">. It is good to get students to deduce (rather than learn) the general equation:<br><br>C<sub>x</sub>H<sub>y</sub> + (x + y/4)O<sub>2</sub>(g) &rarr; xCO<sub>2</sub>(g) + y/2H<sub>2</sub>O(l)<br><br>I&#39;m not so happy about them writing equations for incomplete combustion as who knows what the ratio of carbon, carbon monoxide and carbon dioxide will be in the product mixture.</span></span> They should understand that the reason why the combustion reactions are so exothermic is due to the strength of the O-H and C=O bonds in the products compared to the O=O, C-C and C-H bonds in the reactants.</p><p><span style=""><span style="font-weight: normal;">Show them a <a href="http://youtu.be/nz03fpullyo">video of methane reacting with chlorine</a> to demonstrate how explosive (and therefore how fast) the reaction can be. This is the best place to introduce them to free-radical mechanisms and you can get them to work out the propagation steps for the successive substitution of chlorine for hydrogen to eventually end up with tetrachloromethane. Stress that the mechanism never involves a hydrogen radical - this should help them when it comes to multiple choice questions. It is also good to relate the free radical mechanism with ozone depletion and the reasons why the use of CFCs was banned in the Montreal protocol.</span></span></p><p>I like to give them hands on practical experience of combustion (I compare cyclohexane with cyclohexene) and also the addition reaction with bromine water. Note that alkanes do in fact react with bromine but only by a free-radical mechanism in the presence of ultraviolet light. The addition reaction with bromine water is much faster and so it does make a good test to distinguish between alkanes and alkenes. The product is actually 2-bromocyclohexanol rather than 1,2-dibromocyclohexane but I don&#39;t think that the IB require this amount of detail - probably a note to this effect should have been added in the guidance section.</p><p>Addition polymerization reactions are fairly straightforward at this level. All students really need to know is how to draw the repeating polymer. Make sure that they realise it is only every alternate carbon atom that has the chlorine or methyl group attached in the examples of poly(chloroethene) and poly(propene) respectively. Also note the IUPAC way of writing polymers with the monomer given inside brackets. The importance of addition reactions in society and some useful &#39;Aim 8&#39; chemistry can be discussed here. For example when hydrogenating oils containing unsaturated fatty acids some instead of becoming saturaturated are converted into the trans isomer which increases the amount of low density cholestrol (bad cholesterol) in the body responsible for heart and circulatory problems.</p><hr class="hidden"></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal; "><strong>Study guide</strong></span></b></h4><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><img alt="" src="../../../ib/chemistry/images/2014%20Basic%20information/New%20cover.jpg" style="width: 67px; height: 96px;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><b><span style="font-weight: normal;">Pages </span></b><span style="font-weight: normal;">85 &amp; 86</span></p><hr class="hidden"><h2>Questions</h2><p>For ten &#39;quiz&#39; multiple choice questions with the answers explained see <a href="../24750/mc-test-alkanes-alkenes-addition-polymers-1.html" title="Core &amp; AHL » Teaching each topic &amp; sub-topic » Topics 10 &amp; 20 » Alkanes, alkenes &amp; addition polymers » MC test: Alkanes, alkenes &amp; addition polymers">MC test: Alkanes, alkenes &amp; addition polymers</a>.</p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;">For short-answer questions on alkanes which can be set as an assignment for a test, homework or given for self study together with model answers see <a href="../41121/alkanes-questions-1.html" title="Core &amp; AHL » Teaching each topic &amp; sub-topic » Topics 10 &amp; 20 » Alkanes, alkenes &amp; addition polymers » Alkanes questions">Alkanes questions</a>.</p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;">For short-answer questions on alkenes which can be set as an assignment for a test, homework or given for self study together with model answers see <a href="../41124/alkenes-questions-1.html" title="Core &amp; AHL » Teaching each topic &amp; sub-topic » Topics 10 &amp; 20 » Alkanes, alkenes &amp; addition polymers » Alkenes questions">Alkenes questions</a>.</p><hr class="hidden"><h4><span style=""><b><span style="font-weight: normal;"><strong>Vocabulary list</strong></span></b></span></h4><p><strong><span style=""><span style="font-weight: normal;">homolytic fission<br>heterolytic fission<br>free radical<br>initiation step<br>propagation step<br>termination step</span></span></strong><br>addition reaction<br>hydrogenation<br>hydration<br>halogenation<br>symmetrical alkene<br>addition polymerization<br>poly(ethene)<br>poly(chloroethene)<br>poly(propene)</p><hr class="hidden"><h4><strong><strong>IM, TOK, Utilization etc.</strong></strong></h4><p>See <a href="../18420/topics-10-20-1.html" title="New 2014 programme (First exams 2016) » Core &amp; AHL » Incorporating IM, TOK, 'Utilization' etc. » Topics 10 &amp; 20">separate page </a>which covers all of Topic 10</p><hr class="hidden"><h2><span style=""><b><span style="font-weight: normal;"><strong>Practical work</strong></span></b></span></h2><p><a href="../18598/reactions-of-organic-compounds-1.html"><span style=""><span style="font-weight: normal;"><img class="ico" src="../../../img/icons/lab-1.png"> <strong>Reactions of organic compounds</strong></span></span></a></p><p>Note that cyclohexene is used as an example of an alkene (as it can be compared with cyclohexane and methylbenzene) but cycloalkanes are not strictly on the syllabus.</p><hr class="hidden"></td></tr></tbody></table></div><hr class="hidden"><div class="greenBg"><h2 id="header-13">Teaching slides</h2><p>Teachers may wish to share these slides with students for learning or for reviewing key concepts.</p><div id="myCarousel-14" class="carousel slide" data-id="313"><!-- Carousel items --><div class="carousel-inner"><div class="active item"><a class="fancy" href="../../../tib-galleries/3-313/1021.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/1021.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/1022.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/1022.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/1023.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/1023.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/1024.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/1024.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/1025.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/1025.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/1026.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/1026.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/1027.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/1027.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/screen-shot-2017-01-04-at-092547.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/screen-shot-2017-01-04-at-092547.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/1029.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/1029.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/10210.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/10210.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-313/10211.png" rel="gallery-313" title=""><img alt="" src="files/tib-galleries/3-313/10211.png"></a><div class="carousel-caption"><p>Alkanes, alkenes & addition polymers: </p></div></div></div><!-- Carousel nav --><a class="carousel-control left" href="#myCarousel-14" data-slide="prev">&lsaquo;</a><a class="carousel-control right" href="#myCarousel-14" data-slide="next">&rsaquo;</a><div class="tib-indicators"><img class="" title="Click to view" style="margin: 10px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/1021-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/1022-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/1023-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/1024-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/1025-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/1026-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/1027-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/screen-shot-2017-01-04-at-092547-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/1029-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/10210-thumb128.jpg"><img class="" title="Click to view" style="margin: 5px 4px; width: 48px; height: 48px;" alt="" src="files/tib-galleries/3-313/10211-thumb128.jpg"></div></div><p>&nbsp;&nbsp;</p></div><hr class="hidden"><div class="blueBg"><h2><span style="font-weight: bold;">Other resources</span></h2><p><strong>1. </strong>The explosive reaction between chlorine and methane (although heat rather than ultraviolet light is used to initiate the reaction).</p><p style="text-align: center;"><object height="280" width="360"><param name="quality" value="high"><param name="allowScriptAccess" value="always"><param name="movie" value="http://www.youtube.com/v/nz03fpullyo?version=3&hl=en_US&rel=0"><param name="allowscriptaccess" value="always"><embed allowscriptaccess="always" height="280" quality="high" src="http://www.youtube.com/v/nz03fpullyo?version=3&hl=en_US&rel=0" type="application/x-shockwave-flash" width="360"></object></p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/nz03fpullyo?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/nz03fpullyo">Chlorine + methane reaction <img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-1" name="video-1">&nbsp;</span></a></p><p style="text-align: center;"></p><hr class="hidden"><p><strong>2.</strong> Students who really find balancing equations difficult might find some use for this simple video on balancing complete and incomplete hydrocarbon combustion reactions.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/MCfc4swkILk?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/MCfc4swkILk">Balancing combustion equations <img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-2" name="video-2">&nbsp;</span></a></p><hr class="hidden"><p><strong>3.</strong> A video by Richard Thornley showing simply how addition polymerization occurs for the three cases required by the IB and how to draw the repeating unit. He does, however, omit to put the brackets around the monomer when naming polymers, i.e. IUPAC now recommends poly(ethene) rather than polythene.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/LYZP9LQd-do" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/LYZP9LQd-do" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-3" name="video-3">&nbsp;</span> Polymerisation of alkenes</a><a href="http://youtu.be/LYZP9LQd-do"> </a></p><hr class="hidden"><p><strong>4. </strong>In some countries the use of bromine water is prohibited. If this is the case you may need to show them a video although, of course, it is much better if your students can perform the experiment for themselves.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/2C_6ax2TsV8" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/2C_6ax2TsV8" target="_blank" title="Videos"><img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-4" name="video-4">&nbsp;</span> Test for unsaturation </a></p><hr class="hidden"><p><strong>5.</strong> Many videos on ethanol production are concerned more with biofuels which involves fermentation. One simulation from the <a href="http://demonstrations.wolfram.com/SynthesisOfEthanolByHydrationOfEthylene/">Wolfram Demonstrations Project</a> demonstrates the hydration of ethylene (<em>sic</em>). 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