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<title>DP Chemistry: Rate expression & reaction mechanism</title>
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<meta name="description" content="1. I was searching around on the Internet and came across a worksheet with questions on the rate expression.The first two questions are1) Write the following for the reaction N2 + 3H2 → 2NH32) The rate constant for the reaction HNO3 + NH3 → NH4NO3 is 14.5 L / mol.sec.If the concentration of nitric acid is 0.050 M and the concentration of ammonia is 0.10 M, what will the rate of thisreaction be?">
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href="../19290/introduction-to-biochemistry--1.html">Introduction to biochemistry </a></li><li><a href="../19287/proteins-enzymes--1.html">Proteins & enzymes </a></li><li><a href="../19291/lipids-1.html">Lipids</a></li><li><a href="../19299/carbohydrates--1.html">Carbohydrates </a></li><li><a href="../19305/vitamins--1.html">Vitamins </a></li><li><a href="../19313/biochemistry-the-environment--1.html">Biochemistry & the environment </a></li><li><a href="../19336/proteins-enzymes-ahl--1.html">Proteins & enzymes (AHL) </a></li><li><a href="../19347/nucleic-acids--1.html">Nucleic acids </a></li><li><a href="../19361/biological-pigments--1.html">Biological pigments </a></li><li><a href="../19366/stereochemistry-in-biomolecules-1.html">Stereochemistry in biomolecules</a></li></ul></li><li><a href="../19390/option-c--1.html" class="father">Option C </a><ul class="level-2"><li><a href="../19391/energy-sources-1.html">Energy sources</a></li><li><a href="../19407/fossil-fuels-1.html">Fossil fuels</a></li><li><a href="../19411/nuclear-fusion-nuclear-fission-reactions-1.html">Nuclear fusion & nuclear fission reactions</a></li><li><a href="../19429/solar-energy-1.html">Solar energy</a></li><li><a href="../19437/environmental-impact-global-warming-1.html">Environmental impact - global warming</a></li><li><a href="../19453/electrochemistry-rechargeable-batteries-fuel-cells-1.html">Electrochemistry, rechargeable batteries & fuel cells</a></li><li><a href="../19458/nuclear-fusion-fission-hl--1.html">Nuclear fusion & fission (HL) </a></li><li><a href="../19470/photovoltaic-cells-and-dsscs-1.html">Photovoltaic cells and DSSCs</a></li></ul></li><li><a href="../19078/option-d-1.html" class="father">Option D</a><ul class="level-2"><li><a href="../19079/pharmaceutical-products-drug-action--1.html">Pharmaceutical products & drug action </a></li><li><a href="../19158/aspirin-penicillin--1.html">Aspirin & penicillin </a></li><li><a href="../19174/opiates-1.html">Opiates</a></li><li><a href="../19184/ph-regulation-of-the-stomach-1.html">pH regulation of the stomach</a></li><li><a href="../19194/antiviral-medications--1.html">Antiviral medications </a></li><li><a href="../19211/environmental-impact-of-some-medications-1.html">Environmental impact of some medications</a></li><li><a href="../19254/taxol-a-chiral-auxiliary-case-study-1.html">Taxol - a chiral auxiliary case study</a></li><li><a href="../19258/nuclear-medicine--1.html">Nuclear medicine </a></li><li><a href="../19273/drug-detection-analysis--1.html">Drug detection & analysis </a></li></ul></li></ul></li><li><a href="../16592/practical-scheme-of-work-ia--1.html">Practical scheme of work & IA </a><ul class="level-1"><li><a href="../16682/internal-assessment-1.html" class="father">Internal Assessment</a><ul class="level-2"><li><a href="../18892/scaffolding-the-investigation-1.html">'Scaffolding' the investigation</a></li><li><a href="../18896/timing-organisation--1.html">Timing & organisation </a></li><li><a href="../18905/choosing-the-research-question-1.html">Choosing the research question</a></li><li><a href="../18946/personal-engagement-1.html">Personal engagement</a></li><li><a href="../18950/exploration-1.html">Exploration</a></li><li><a href="../18957/analysis-1.html">Analysis</a></li><li><a href="../18965/evaluation-1.html">Evaluation</a></li><li><a href="../18966/communication-1.html">Communication</a></li><li><a href="../19882/internal-standardization-of-the-ia-1.html">Internal standardization of the IA</a></li><li><a href="../19901/submitting-the-samples-for-moderation-2.html">Submitting the samples for moderation</a></li><li><a href="../33754/ten-suggestions-for-ias-using-secondary-data-1.html">Ten suggestions for IAs using secondary data</a></li><li><a href="../37544/gaining-full-marks-for-a-databased-ia--1.html">Gaining full marks for a databased IA </a></li><li><a href="../19506/ia-example-marking-exercise--1.html">IA example & marking exercise </a></li><li><a href="../23929/genuine-examples-of-moderated-ia-reports-1.html">Genuine examples of moderated IA reports</a></li><li><a href="../25234/examples-of-teacher-marked-ia-reports--1.html">Examples of teacher-marked IA reports </a></li><li><a href="../37542/history-of-internal-assessment-1.html">History of Internal Assessment</a></li></ul></li><li><a href="../16598/mandatory-laboratory-components-1.html" class="father">Mandatory laboratory components</a><ul class="level-2"><li><a href="../16613/formula-of-magnesium-oxide--1.html">Formula of magnesium oxide </a></li><li><a href="../16612/determining-the-mr-of-an-unknown-gas-1.html">Determining the <i>M</i><sub>r</sub> of an unknown gas</a></li><li><a href="../16615/acid-base-titrations--1.html">Acid-base titrations </a></li><li><a href="../16616/a-green-acid-base-practical-1.html">A green acid-base practical</a></li><li><a href="../16617/analysis-of-aspirin-tablets-1.html">Analysis of aspirin tablets</a></li><li><a href="../16618/caco3-in-egg-shells-1.html">CaCO<sub>3</sub> in egg shells</a></li><li><a href="../16644/enthalpy-changes-1.html">Enthalpy changes</a></li><li><a href="../16631/reaction-rates-1.html">Reaction rates</a></li><li><a href="../16635/rate-dependent-factors-1.html">Rate-dependent factors</a></li><li><a href="../16636/determining-ea-for-a-reaction-1.html">Determining <i>E</i><sub>a</sub> for a reaction</a></li><li><a href="../16637/iodination-of-propanone-1.html">Iodination of propanone</a></li><li><a href="../18144/titrations-with-a-ph-meter-1.html">Titrations with a pH meter</a></li><li><a href="../18355/redox-titration-with-kmno4--1.html">Redox titration with KMnO<sub>4</sub> </a></li><li><a href="../16640/voltaic-cells-1.html">Voltaic cells</a></li><li><a href="../16659/3-d-molecular-modelling--1.html">3-D molecular modelling </a></li></ul></li><li><a href="../17168/other-good-practicals-1.html" class="father">Other good practicals</a><ul class="level-2"><li><a href="../17196/common-chemical-reactions-1.html">Common chemical reactions</a></li><li><a href="../227/elements-oxides-of-the-third-period--1.html">Elements & oxides of the third period </a></li><li><a href="../17239/the-halogens-1.html">The halogens</a></li><li><a href="../17162/boiling-points-of-mixtures-1.html">Boiling points of mixtures</a></li><li><a href="../17170/polarity-of-molecules-1.html">Polarity of molecules</a></li><li><a href="../18083/le-chateliers-principle--1.html">Le Chatelier's principle </a></li><li><a href="../19582/determining-kc-for-an-esterification-reaction-1.html">Determining <i>K</i><sub>c</sub> for an esterification reaction</a></li><li><a href="../18164/redox-reactions-of-vanadium--1.html">Redox reactions of vanadium </a></li><li><a href="../18351/chlorine-in-swimming-pools--1.html">Chlorine in swimming pools </a></li><li><a href="../18178/analysis-of-cuii-ions-in-solution--1.html">Analysis of Cu(II) ions in solution </a></li><li><a href="../18179/percentage-of-copper-in-brass-1.html">Percentage of copper in brass</a></li><li><a href="../18356/electrolytic-cells--1.html">Electrolytic cells </a></li><li><a href="../18598/reactions-of-organic-compounds-1.html">Reactions of organic compounds</a></li><li><a href="../18752/hydrolysis-of-halogenoalkanes-1.html">Hydrolysis of halogenoalkanes</a></li><li><a href="../18784/preparation-of-13-dinitrobenzene--1.html">Preparation of 1,3-dinitrobenzene </a></li><li><a href="../19022/determination-of-an-organic-structure-1.html">Determination of an organic structure</a></li><li><a href="../19887/preparation-of-nylon-66-1.html">Preparation of nylon 6,6</a></li><li><a href="../19343/determination-of-vitamin-c-content--1.html">Determination of vitamin C content </a></li><li><a href="../19342/hydrolysis-of-starch--1.html">Hydrolysis of starch </a></li><li><a href="../19159/preparation-purification-of-aspirin--1.html">Preparation & purification of aspirin </a></li></ul></li><li><a href="../18851/ict-in-practical-work-1.html" class="father">ICT in practical work</a><ul class="level-2"><li><a href="../18852/data-logging--1.html">Data logging </a></li><li><a href="../18853/software-for-graph-plotting--1.html">Software for graph plotting </a></li><li><a href="../18854/spreadsheets-for-data-processing--1.html">Spreadsheets for data processing </a></li><li><a href="../18855/databases-1.html">Databases</a></li><li><a href="../18856/computer-modelling-simulations--1.html">Computer modelling & simulations </a></li></ul></li><li><a href="../16594/group-4-project-1.html" class="father">Group 4 Project</a><ul class="level-2"><li><a href="../16595/practicalities-1.html">Practicalities</a></li><li><a href="../16596/reflective-statement--2.html">Reflective statement </a></li></ul></li><li><a href="../16666/a-new-laboratory-1.html">A new laboratory?</a></li></ul></li><li><a href="../16284/exams-1.html">Exams</a><ul class="level-1"><li><a href="../16286/essential-facts-1.html" class="father">Essential Facts</a><ul class="level-2"><li><a href="../16287/objectives-command-terms-1.html">Objectives & command terms</a></li><li><a href="../16288/grade-descriptors-1.html">Grade descriptors</a></li><li><a href="../16289/grade-boundaries-1.html">Grade boundaries</a></li></ul></li><li><a href="../16302/paper-1-multiple-choice-1.html" class="father">Paper 1 (Multiple Choice)</a><ul class="level-2"><li><a href="../16303/advice-to-students-paper-1-1.html">Advice to students (Paper 1)</a></li><li><a href="../31515/practice-paper-1-exams-1.html">Practice Paper 1 exams</a></li></ul></li><li><a href="../16305/paper-2-1.html" class="father">Paper 2</a><ul class="level-2"><li><a href="../16306/advice-to-students-paper-2-1.html">Advice to students (Paper 2)</a></li><li><a href="../16307/areas-of-difficulty-1.html">Areas of difficulty</a></li></ul></li><li><a href="../16313/paper-3--1.html" class="father">Paper 3 </a><ul class="level-2"><li><a 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options</a></li><li><a href="../24897/sl-quizzes-on-option-sub-topics--1.html">SL Quizzes on option sub-topics </a></li><li><a href="../17785/hl-multiple-choice-tests-on-individual-topics-1.html">HL Multiple choice tests on individual topics</a></li><li><a href="../24352/hl-multiple-choice-quizzes-on-sub-topics-1.html">HL Multiple choice 'quizzes' on sub-topics</a></li><li><a href="../31520/hl-practice-paper-1-exams--1.html">HL Practice Paper 1 exams </a></li><li><a href="../17787/hl-questions-on-each-sub-topic--1.html">HL Questions on each sub-topic </a></li><li><a href="../20428/hl-paper-3-section-a-questions-1.html">HL Paper 3 Section A questions</a></li><li><a href="../17793/hl-questions-on-the-options-1.html">HL Questions on the options</a></li><li><a href="../24973/hl-quizzes-on-option-sub-topics-1.html">HL Quizzes on option sub-topics</a></li><li><a href="../41573/printable-versions-of-written-tasks--1.html">Printable versions of written tasks </a></li></ul></li><li><a 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"><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24660/mc-test-the-equilibrium-law-1.html" title="MC test: The equilibrium law">MC test: The equilibrium law</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40961/equilibrium-law-questions-1.html" title="Equilibrium law questions">Equilibrium law questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18120/topics-8-18--1.html" title="Topics 8 & 18 ">Topics 8 & 18 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18124/theories-of-acids-bases--1.html" title="Theories of acids & bases ">Theories of acids & bases </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24662/mc-test-theories-of-acids-bases-1.html" title="MC test: Theories of acids & bases">MC test: Theories of acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40963/theories-of-acids-bases-questions-1.html" title="Theories of acids & bases questions">Theories of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18126/properties-of-acids-bases-1.html" title="Properties of acids & bases">Properties of acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24663/mc-test-properties-of-acids-bases--1.html" title="MC test: Properties of acids & bases ">MC test: Properties of acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40964/properties-of-acids-bases-questions-1.html" title="Properties of acids & bases questions">Properties of acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18140/ph-scale-1.html" title="pH scale">pH scale</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24668/mc-test-the-ph-scale-1.html" title="MC test: The pH scale">MC test: The pH scale</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40971/ph-scale-questions-1.html" title="pH scale questions">pH scale questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18152/strong-weak-acids-bases-1.html" title="Strong & weak acids & bases">Strong & weak acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24670/mc-test-strong-weak-acids-bases-1.html" title="MC test: Strong & weak acids & bases">MC test: Strong & weak acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40972/strong-weak-acid-bases-questions-1.html" title="Strong & weak acid & bases questions">Strong & weak acid & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18156/acid-deposition-1.html" title="Acid deposition">Acid deposition</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24674/mc-test-acid-deposition-1.html" title="MC test: Acid deposition">MC test: Acid deposition</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40983/acid-deposition-questions-1.html" title="Acid deposition questions">Acid deposition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18160/lewis-acids-bases-1.html" title="Lewis acids & bases">Lewis acids & bases</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24710/mc-test-lewis-acids-bases-1.html" title="MC test: Lewis acids & bases">MC test: Lewis acids & bases</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40986/lewis-acids-bases-questions-1.html" title="Lewis acids & bases questions">Lewis acids & bases questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18250/acid-base-calculations-1.html" title="Acid base calculations">Acid base calculations</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24714/mc-test-calculations-involving-acids-bases--1.html" title="MC test: Calculations involving acids & bases ">MC test: Calculations involving acids & bases </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../40988/acid-base-calculations-questions--1.html" title="Acid-base calculations questions ">Acid-base calculations questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../26161/ph-titration-curves-1.html" title="pH titration curves">pH titration curves</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../26158/mc-test-ph-curves-1.html" title="MC test: pH curves">MC test: pH curves</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41000/ph-curves-questions--1.html" title="pH curves questions ">pH curves questions </a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18350/topics-9-19-1.html" title="Topics 9 & 19">Topics 9 & 19</a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18365/oxidation-reduction-1.html" title="Oxidation & reduction">Oxidation & reduction</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24725/mc-test-oxidation-reduction-1.html" title="MC test: Oxidation & reduction">MC test: Oxidation & reduction</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41033/oxidation-reduction-questions-1--1.html" title="Oxidation & reduction questions (1) ">Oxidation & reduction questions (1) </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41034/oxidation-reduction-questions-2-1.html" title="Oxidation & reduction questions (2)">Oxidation & reduction questions (2)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41035/oxidation-reduction-questions-3-1.html" title="Oxidation & reduction questions (3)">Oxidation & reduction questions (3)</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18383/electrochemical-cells-1.html" title="Electrochemical cells">Electrochemical cells</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24740/mc-test-electrochemical-cells-1.html" title="MC test: Electrochemical cells">MC test: Electrochemical cells</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41072/electrochemical-cells-questions--1.html" title="Electrochemical cells questions ">Electrochemical cells questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18401/electrochemical-cells-ahl--1.html" title="Electrochemical cells (AHL) ">Electrochemical cells (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24742/mc-test-electrochemical-cells-ahl-1.html" title="MC test: Electrochemical cells (AHL)">MC test: Electrochemical cells (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41098/electrochemical-cells-1-ahl-questions-1.html" title="Electrochemical cells (1) (AHL) questions">Electrochemical cells (1) (AHL) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41099/electrochemical-cells-2-ahl-questions-1.html" title="Electrochemical cells (2) (AHL) questions">Electrochemical cells (2) (AHL) questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../18475/topics-10-20--1.html" title="Topics 10 & 20 ">Topics 10 & 20 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18497/fundamentals-of-organic-chemistry--1.html" title="Fundamentals of organic chemistry ">Fundamentals of organic chemistry </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24749/mc-test-fundamentals-of-organic-chemistry-1.html" title="MC test: Fundamentals of organic chemistry">MC test: Fundamentals of organic chemistry</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41111/fundamentals-of-organic-chemistry-1-questions-1.html" title="Fundamentals of organic chemistry (1) questions">Fundamentals of organic chemistry (1) questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41112/fundamentals-of-organic-chemistry-2-questions-1.html" title="Fundamentals of organic chemistry (2) questions">Fundamentals of organic chemistry (2) questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18597/alkanes-alkenes-addition-polymers-1.html" title="Alkanes, alkenes & addition polymers">Alkanes, alkenes & addition polymers</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24750/mc-test-alkanes-alkenes-addition-polymers-1.html" title="MC test: Alkanes, alkenes & addition polymers">MC test: Alkanes, alkenes & addition polymers</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41121/alkanes-questions-1.html" title="Alkanes questions">Alkanes questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41124/alkenes-questions-1.html" title="Alkenes questions">Alkenes questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18741/alcohols--1.html" title="Alcohols ">Alcohols </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24772/mc-test-alcohols-1.html" title="MC test: Alcohols">MC test: Alcohols</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41125/alcohols-questions-1.html" title="Alcohols questions">Alcohols questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18742/halogenoalkanes-benzene--1.html" title="Halogenoalkanes & benzene ">Halogenoalkanes & benzene </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24797/mc-test-halogenoalkanes-benzene-1.html" title="MC test: Halogenoalkanes & benzene">MC test: Halogenoalkanes & benzene</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41130/halogenoalkanes-benzene-questions-1.html" title="Halogenoalkanes & benzene questions">Halogenoalkanes & benzene questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18762/nucleophilic-substitution--1.html" title="Nucleophilic substitution ">Nucleophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24757/mc-test-nucleophilic-substitution-1.html" title="MC test: Nucleophilic substitution">MC test: Nucleophilic substitution</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41138/nucleophilic-substitution-questions-1.html" title="Nucleophilic substitution questions">Nucleophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18766/electrophilic-addition--1.html" title="Electrophilic addition ">Electrophilic addition </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24805/mc-test-electrophilic-addition-electrophilic-substitution-reacti-2.html" title="MC test: Electrophilic addition & electrophilic substitution reactions">MC test: Electrophilic addition & electrophilic substitution reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41148/electrophilic-addition-questions-1.html" title="Electrophilic addition questions">Electrophilic addition questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18780/electrophilic-substitution--2.html" title="Electrophilic substitution ">Electrophilic substitution </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41149/electrophilic-substitution-questions-1.html" title="Electrophilic substitution questions">Electrophilic substitution questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18793/reduction-reactions--1.html" title="Reduction reactions ">Reduction reactions </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24811/mc-test-reduction-reactions-1.html" title="MC test: Reduction reactions">MC test: Reduction reactions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41150/reduction-reactions-questions-1.html" title="Reduction reactions questions">Reduction reactions questions</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18797/synthetic-routes--1.html" title="Synthetic routes ">Synthetic routes </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24822/mc-test-synthetic-routes-1.html" title="MC test: Synthetic routes">MC test: Synthetic routes</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41152/synthetic-routes-questions--1.html" title="Synthetic routes questions ">Synthetic routes questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18844/stereoisomerism--1.html" title="Stereoisomerism ">Stereoisomerism </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24817/mc-test-stereoisomerism-1.html" title="MC test: Stereoisomerism">MC test: Stereoisomerism</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../41166/stereoisomerism-questions-1.html" title="Stereoisomerism questions">Stereoisomerism questions</a></li></ul></ul><li class=" parent" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../17285/topics-11-21--1.html" title="Topics 11 & 21 ">Topics 11 & 21 </a></li><ul class="level-2 "><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../17276/uncertainty-errors--1.html" title="Uncertainty & errors ">Uncertainty & errors </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24818/mc-test-uncertainties-errors-1.html" title="MC test: Uncertainties & errors">MC test: Uncertainties & errors</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../38869/uncertainty-error-questions--1.html" title="Uncertainty & error questions ">Uncertainty & error questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../15014/graphical-techniques-1.html" title="Graphical techniques">Graphical techniques</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24819/mc-test-graphical-techniques-1.html" title="MC test: Graphical techniques">MC test: Graphical techniques</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39387/graphical-techniques-questions--1.html" title="Graphical techniques questions ">Graphical techniques questions </a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../18968/spectroscopic-identification-of-organic-compounds-1.html" title="Spectroscopic identification of organic compounds">Spectroscopic identification of organic compounds</a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24820/mc-test-spectroscopic-identification-of-organic-compounds--1.html" title="MC test: Spectroscopic identification of organic compounds ">MC test: Spectroscopic identification of organic compounds </a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39388/index-of-hydrogen-deficiency-questions-1.html" title="Index of hydrogen deficiency questions">Index of hydrogen deficiency questions</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39351/identification-from-spectra-question-1-1.html" title="Identification from spectra - Question 1">Identification from spectra - Question 1</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39353/identification-from-spectra-question-2-1.html" title="Identification from spectra - Question 2">Identification from spectra - Question 2</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39354/identification-from-spectra-question-3-1.html" title="Identification from spectra - Question 3">Identification from spectra - Question 3</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39355/identification-from-spectra-question-4-1.html" title="Identification from spectra - Question 4">Identification from spectra - Question 4</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39356/identification-from-spectra-question-5-1.html" title="Identification from spectra - Question 5">Identification from spectra - Question 5</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39357/identification-from-spectra-question-6-1.html" title="Identification from spectra - Question 6">Identification from spectra - Question 6</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39358/identification-from-spectra-question-7-1.html" title="Identification from spectra - Question 7">Identification from spectra - Question 7</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39359/identification-from-spectra-question-8-1.html" title="Identification from spectra - Question 8">Identification from spectra - Question 8</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39360/identification-from-spectra-question-9-1.html" title="Identification from spectra - Question 9">Identification from spectra - Question 9</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39361/identification-from-spectra-question-10-1.html" title="Identification from spectra - Question 10">Identification from spectra - Question 10</a></li></ul><li class=" parent" style="padding-left: 28px"><i class="expander fa fa-caret-right "></i><a href="../19027/spectroscopic-identification-of-organic-compounds-ahl--1.html" title="Spectroscopic identification of organic compounds (AHL) ">Spectroscopic identification of organic compounds (AHL) </a></li><ul class="level-3 "><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../24821/mc-test-spectroscopic-identification-of-organic-compounds-ahl-1.html" title="MC test: Spectroscopic identification of organic compounds (AHL)">MC test: Spectroscopic identification of organic compounds (AHL)</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39375/identification-from-spectra-question-11-1.html" title="Identification from spectra - Question 11">Identification from spectra - Question 11</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39376/identification-from-spectra-question-12-1.html" title="Identification from spectra - Question 12">Identification from spectra - Question 12</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39377/identification-from-spectra-question-13-1.html" title="Identification from spectra - Question 13">Identification from spectra - Question 13</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39378/identification-from-spectra-question-14-1.html" title="Identification from spectra - Question 14">Identification from spectra - Question 14</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39379/identification-from-spectra-question-15-1.html" title="Identification from spectra - Question 15">Identification from spectra - Question 15</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39380/identification-from-spectra-question-16-1.html" title="Identification from spectra - Question 16">Identification from spectra - Question 16</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39381/identification-from-spectra-question-17-1.html" title="Identification from spectra - Question 17">Identification from spectra - Question 17</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39382/identification-from-spectra-question-18-1.html" title="Identification from spectra - Question 18">Identification from spectra - Question 18</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39383/identification-from-spectra-question-19-1.html" title="Identification from spectra - Question 19">Identification from spectra - Question 19</a></li><li class="" style="padding-left: 42px"><i class="expander fa fa-caret-right "></i><a href="../39385/identification-from-spectra-question-20-1.html" title="Identification from spectra - Question 20">Identification from spectra - Question 20</a></li></ul></ul></ul><li class=" parent" style="padding-left: 0px"><i class="expander fa fa-caret-right "></i><a href="../16441/the-nature-of-science-1.html" title="The Nature of Science">The Nature of Science</a></li><ul class="level-1 "><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../16450/key-terms-concepts-1.html" title="Key terms & concepts">Key terms & concepts</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../34566/nos-critical-thinking-1.html" title="NOS & Critical Thinking">NOS & Critical Thinking</a></li><li class="" style="padding-left: 14px"><i class="expander fa fa-caret-right "></i><a href="../32100/how-the-elements-were-named-1.html" title="How the elements were named">How the elements were named</a></li><li class="" 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I was searching around on the Internet and came across a worksheet with questions on the rate expression.The first two questions are1) Write the following for the reaction N2 + 3H2 → 2NH32) The rate constant for the...%0Ahttps%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F17870%2Frate-expression-reaction-mechanism"><i class="fa fa-envelope"></i><span>Email</span></a></li></ul></li><li><a class="" href="chemistry/teaching-materials"><i class="fa fa-puzzle-piece colored"></i></a></li></ul></div></div><h1 class="section-title">Rate expression & reaction mechanism</h1><ul class="breadcrumb"><li><a title="Home" href="https://www.thinkib.net/chemistry"><i class="fa fa-home"></i></a><span class="divider"><i class="fa fa-chevron-right"></i></span></li><li><a title="Go to: Core & AHL" href="../16347/core-ahl-1.html">Core & AHL</a><span class="divider"><i class="fa fa-chevron-right"></i></span></li><li><a title="Go to: Teaching each topic & sub-topic" href="../16329/teaching-each-topic-sub-topic-1.html">Teaching each topic & sub-topic</a><span class="divider"><i class="fa fa-chevron-right"></i></span></li><li><a title="Go to: Topics 6 & 16" href="../17848/topics-6-16-1.html">Topics 6 & 16</a><span class="divider"><i class="fa fa-chevron-right"></i></span></li><li><span>Rate expression & reaction mechanism</span></li></ul><div id="std-sidebox-task-added-msg"></div><div id="modal-feedback" class="modal hide fade text-left" tabindex="-1" role="dialog" aria-labelledby="log-in form" aria-hidden="true">
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</div><section id="main-content"><div id="toc-1672972904" class="toc"><a href="#" class="toc-switcher" title="Show table of contents"><small><i class="fa fa-reorder"></i> Table of contents <span class="pull-right"><i class="fa fa-chevron-down"></i></span></small></a></div><h1><img class="ico" src="../../../img/icons/higher-1.png"> 16.1 Rate expression & reaction mechanism (4 hours)</h1><div class="pinkBg"><div><h2>Pause for thought</h2><p><strong>1.</strong> I was searching around on the Internet and came across <a href="../../../HH015.doc">a worksheet</a> with questions on the rate expression.</p><p>The first two questions are</p><p>1) Write the following for the reaction N<sub>2</sub> + 3H<sub>2</sub> → 2NH<sub>3</sub></p><ul><li>The rate expression for the reaction</li><li>The order of the reaction in each of the reagents</li><li>The overall order of the reaction</li></ul><p>2) The rate constant for the reaction HNO<sub>3</sub> + NH<sub>3</sub> → NH<sub>4</sub>NO<sub>3</sub> is 14.5 L / mol.sec.<br>If the concentration of nitric acid is 0.050 M and the concentration of ammonia is 0.10 M, what will the rate of this<br>reaction be?</p><p>The answers are then given:</p><p>1).</p><ul><li>Rate = k[N<sub>2</sub>][H<sub>2</sub>]<sup>3</sup></li><li>The reaction is first order in nitrogen and third order in hydrogen.</li><li>The overall order of the reaction is fourth order</li></ul><p>2). Rate = k[HNO<sub>3</sub>][NH<sub>3</sub>]</p><p>Rate = (14.5 L / mol.sec)(0.050 M)(0.10 M)</p><p>Rate = 0.073 mol / L. sec</p><p><img alt="" class="right noborder" height="255" src="../../../ib/chemistry/images/Core%20and%20AHL/Kinetics/Habers%20apparatus.jpg" title="The apparatus devised by Fritz Haber to synthesise ammonia from nitrogen and hydrogen" width="315">The question uses M and L /mol. sec whereas we use mol dm<sup>-3</sup> and dm<sup>-3</sup> mol <sup>-1</sup> s<sup>-1</sup> and no states are given and <em>k</em> is not in italics but all that is only a question of convention. What is completely wrong is that these questions are unanswerable with the information given. Rate expressions <strong>cannot be determined from the stoichiometric equation</strong>. They can only be arrived at from experimental data.</p><p>The rate equation for the first question can only be expressed as:</p><p>rate = <em>k</em>[N<sub>2</sub>]<em><sup>x</sup></em>[H<sub>2</sub>]<em><sup>y </sup></em></p><p>where<sup> </sup> <em>x</em> and <em>y</em> are the order of the reaction with respect to nitrogen and hydrogen and must be found by experiment.</p><p><br>In fact work by <a href="http://www.sciencedirect.com/science/article/pii/0021951777902378">Ertl and others</a> have shown that in the Haber Process (right) where an iron catalyst is used the reaction is complex and thought to proceed by the following steps:</p><ol><li>N<sub>2</sub> (g) → N<sub>2</sub> (adsorbed)</li><li>N<sub>2</sub> (adsorbed) → 2 N (adsorbed)</li><li>H<sub>2</sub>(g) → H<sub>2</sub> (adsorbed)</li><li>H<sub>2</sub> (adsorbed) → 2 H (adsorbed)</li><li>N (adsorbed) + 3 H(adsorbed)→ NH<sub>3</sub> (adsorbed)</li><li>NH<sub>3</sub> (adsorbed) → NH<sub>3</sub> (g)</li></ol><p>The second step is the slowest step which suggests that [H<sub>2</sub>] does not even appear in the rate equation.</p><p>Another example to illustrate the same point is the reaction of hydrogen with halogens:</p><p>H<sub>2</sub>(g) + X<sub>2</sub>(g) → 2HX(g)</p><p>When X is iodine, the experimentally determined rate expression looks as if it could be deduced from the stoichiometric equation as it is:</p><p>rate = <em>k</em>[H<sub>2</sub>(g)][l<sub>2</sub>(g)]</p><p>but it is very different case when bromine is involved</p><p>rate = <em>k</em>[H<sub>2</sub>(g)][Br<sub>2</sub>(g)]<sup>½</sup> / ([Br<sub>2</sub>(g)] + <em>k</em>'[HBr(g)]</p><hr class="hidden"><p><strong>2.</strong> Just a question concerning reaction mechanisms that a student of mine once asked which you might like to reflect upon.</p><p>We were looking at nucleophilic substitution reactions and specifically why the hydroxide ion is a better nucleophile than water. During the discussion I confirmed the answer given by most of the students that the hydroxide ion is more electron rich and therefore it will be attracted more strongly to the δ+ carbon atom of the halogenoalkane. Her question was: How can we know that hydroxide ions are better nucleophiles than water in the case of tertiary halogenoalkanes? She argued that when the halogenoalkane is tertiary the first step in the reaction is the dissociation of the halogenoalkane into the halogen ion and the tertiary carbocation. Since this is a first order reaction with the rate only depending upon the concentration of the halogenoalkane the first step is the slow step in the reaction. Therefore the nucleophile will play no part in the overall rate and so there should be no difference in the rate when either water or hydroxide ions are used as the nucleophile.</p><p>S<sub>N</sub>2 mechanism. The better nucleophile should give a faster rate as both the nucleophile and the halogenoalkane are involved in the rate determining step:</p><p style="text-align: center;"><img alt="" class="noborder" height="115" src="../../../ib/chemistry/images/Core%20and%20AHL/Kinetics/SN2%20mechanism%20.jpg" title="SN2 mechanism" width="682"></p><p>S<sub>N</sub>1 mechanism. The first step is the slow step with only the halogenoalkane involved:</p><p style="text-align: center;"><img alt="" class="noborder" height="126" src="../../../ib/chemistry/images/Core%20and%20AHL/Kinetics/SN1%20mechanism.jpg" title="First step of SN1 mechanism - the slow step" width="607"></p><p>Since the second step is faster the nature of the nucleophile should make no difference to the overall rate of the reaction so it is impossible to determine which is the better nucleophile in this situation:</p><p style="text-align: center;"><img alt="" class="noborder" height="145" src="../../../ib/chemistry/images/Core%20and%20AHL/Kinetics/SN1%20mechanism1.jpg" title="Th esecond step of an SN1 mechanism - the faster step" width="529"></p><p>She was a smart student!</p><hr class="hidden"></div></div><hr class="hidden"><div class="box"><h2><strong>Nature of Science</strong></h2><p>Rather like 6.1 : Collision theory and rates of reaction, this sub-topic also provides a good example of the Principle of Occam’s razor. As theories develop they need to remain as simple as possible while maximizing their powers of explanation. Because the probability of collisions between three reacting species is low it means that stepwise reaction mechanisms are more likely.</p><hr class="hidden"></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h3><b><span style="font-weight: normal; "></span></b></h3><div class="yellowBg"><div><h2><b><span style="font-weight: normal; "><strong>Learning outcomes</strong></span></b></h2><p><span style="font-weight: normal; ">After studying this topic students should be able to:</span></p><p><b><span style="font-weight: normal; "><strong>Understand</strong></span></b></p><ul><li>Reactions may involve more than one step and the slowest step determines the rate of reaction (This step is known as the rate determining step/RDS).</li><li>The number of reactant particles taking part in any specified step is known as the molecularity.</li><li>The order of a reaction can be either an integer or fractional. The order of a reaction can describe, with respect to a reactant, the number of particles<br>taking part in the rate-determining step.</li><li>All rate equations can only be determined by experiment.</li><li>The units of a rate constant are determined by the overall order of the reaction and the value of the rate constant, <em>k</em>, is affected by temperature.</li><li>Catalysts alter a reaction mechanism by producing a step with a lower activation energy.</li></ul><p><strong>Apply their knowledge to:</strong></p><ul><li>Deduce the rate expression for an equation from experimental data and solve problems involving the rate expression.</li><li>Sketch, identify, and analyse graphical representations for zero, first and second order reactions.</li><li>Evaluate proposed reaction mechanisms to show they are (or are not) consistent with kinetic and<br>stoichiometric data.</li></ul></div></div></td><td style="width: 50%;" valign="top"><div class="yellowBg"><div><h4><strong><strong>Clarification notes</strong></strong></h4><p>Calculations will only involve orders with whole number values.<br>Concentration–time and rate–concentration graphs should be considered.<br>Potential energy level profiles should be used to illustrate multi-step reactions. The profile should show the higher <em>E</em><sub>a</sub> in the rate-determining step.<br>Catalysts are involved in the rate-determining step.<br>Consideration should be given to reactions where the rate-determining step is not the first step.<br>An appropriate experiment is one which allows students to vary concentrations in order to see the effect upon the rate and hence determine a rate equation.</p><hr><h4>International-mindedness</h4><p>The first industrial catalyst to be used was for the Contact process to produce sulfuric acid. It has been stated that for a long time the amount of sulfuric acid produced by a country closely mirrored the country’s economic health.<br>What are some of the current indicators for a country’s economic health?</p></div></div></td></tr></tbody></table></div><hr class="hidden"><div class="box"><table align="left" border="0" cellpadding="10" cellspacing="0"><tbody><tr><td style="width: 50%;" valign="top"><h2><span style=""><b><span style="font-weight: normal;"><strong>Teaching tips</strong></span></b></span></h2><p>From the core it is important to stress the definition of rate of reaction as the units, mol dm<sup>-3</sup> s<sup>-1</sup> are crucial when it comes to deducing the different units for the rate constants for zero, first, second and third order reactions.</p><p>Use the example I've given above (or another one) to stress that rate expressions cannot be arrived at just by looking at the stoichiometric equation. They have to be derived from experimental evidence. Use that time old reaction A + B → products to give the general expression rate = <em>k</em>[A]<sup>x</sup>[B]<sup>y</sup> to explain what is meant by order of reaction with respect to a particular reactant and the overall order of reaction. Stress the difference between rate constant (small italic <em>k</em>) and equilibrium constant (large italic <em>K</em>).</p><p>Deducing the order from experimental data almost always for the IB means looking at keeping all the concentrations of the reactants constant and just doubling or tripling one of them selectively to see the effect on the <strong>initial</strong> rate (see the attached questions).</p><p>If students understand the concepts behind rate expression they should be able to deduce the shapes of the concentration v time and rate v concentration graphs for zero, first and second order reactions. It is not specified on the syllabus but it is worth talking about half-life, t<sub>½</sub>, and getting them to realise that this can be used to show whether a reaction is first order by seeing if the half-life on the concentration v time graph is constant.</p><p><span style=""><span style="font-weight: normal;">The most important concept</span></span> for reaction mechanism is that the overall rate of a reaction depends only on the slow step. This is perhaps not immediately obvious to students. I get them to stand in a row and pretend they are on the production line of a factory (e.g. to make cars) with each being given a particular job. As the line rolls past they quickly see that the rate at which cars are produced depends on whoever is slowest, e.g. the one putting the wheels on, and that it doesn't matter how fast the others work the overall rate will not change.</p><p>This topic relates well to the S<sub>N</sub>1 and S<sub>N</sub>2 mechanisms for organic substitution reactions so it is certainly worth making the link (as I have done in 'pause for thought' above).</p><p>Stress that the order of the reaction and hence the rate equation can <strong>only</strong> be determined experimentally. Stress too that it is impossible to prove a mechanism. All that you can do is propose a mechanism that is consistent with the rate equation. Mechanisms cannot be deduced just by looking at the chemical equation for the reaction possible mechanisms <strong>must</strong> be deduced from the rate equation.</p><p>It is worth explaining that collisions between three particles are very unlikely so all rate determining steps will only involve one or two species although one of the species may be an intermediate. The reaction between hydrogen and nitrogen(II) oxide to produce nitrogen and water is a good example of this. The reaction is first order with respect to hydrogen and second order with respect to nitrogen(II) oxide. This is because the mechanism is thought to be:<br>2NO(g) → N<sub>2</sub>O<sub>2</sub>(g)<br>N<sub>2</sub>O<sub>2</sub>(g) + H<sub>2</sub>(g) → N<sub>2</sub>O(g) + H<sub>2</sub>O(g)<br>N<sub>2</sub>O(g) + H<sub>2</sub>(g) → N<sub>2</sub>(g) + H<sub>2</sub>O(g)<br>with the second step being the slowest and hence the rate-determining step. Note that at IB level it would appear safe to assume that [N<sub>2</sub>O<sub>2</sub>(g)] = [NO(g)]<sup>2</sup> from the first step. In fact it should be obtained using the equilibrium constant since <em>K</em><sub>c </sub>= [N<sub>2</sub>O<sub>2</sub>(g)] ÷ [NO(g)]<sup>2 </sup>so strictly speaking [N<sub>2</sub>O<sub>2</sub>(g)] = <em>K</em><sub>c </sub>[NO(g)]<sup>2</sup>.</p></td><td style="width: 50%;" valign="top"><h4><b><span style="font-weight: normal; "><strong>Study guide</strong></span></b></h4><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><img alt="" src="../../../ib/chemistry/images/2014%20Basic%20information/New%20cover.jpg" style="width: 67px; height: 96px;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"><b><span style="font-weight: normal;">Page </span></b><span style="font-weight: normal;">49 - 50</span></p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;"></p><hr class="hidden"><h2>Questions</h2><p>For ten 'quiz' multiple choice questions with the answers explained see <a href="../24645/mctest-rate-expression-reaction-mechanisms.html" title="Core & AHL » Teaching each topic & sub-topic » Topics 6 & 16 » Rate expression & reaction mechanism » MCTest: Rate expression & reaction mechanisms">MCTest: Rate expression & reaction mechanisms</a>.</p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;">For short-answer questions on rate expressions which can be set as an assignment for a test, homework or given for self study together with model answers see <a href="../40949/rate-expression-questions-1.html" title="Core & AHL » Teaching each topic & sub-topic » Topics 6 & 16 » Rate expression & reaction mechanism » Rate expression questions">Rate expression questions</a>.</p><p style="margin: 0px 0px 1em; padding: 0px; color: rgb(0, 0, 0); font-size: 1em;">For short-answer questions on reaction mechanisms which can be set as an assignment for a test, homework or given for self study together with model answers see <a href="../40950/reaction-mechanisms-questions-1.html" title="Core & AHL » Teaching each topic & sub-topic » Topics 6 & 16 » Rate expression & reaction mechanism » Reaction mechanisms questions">Reaction mechanisms questions</a>. </p><hr class="hidden"><h4><span style=""><b><span style="font-weight: normal;"><strong>Vocabulary list</strong></span></b></span></h4><p>rate constant, <em>k</em><br>rate expression<br>rate equation<br>order of reaction<br>overall order<br>half-life, t<sub>½</sub><br>slow step<br>fast step<br>rate-determining step</p><hr class="hidden"><h4><strong><strong>IM, TOK, 'Utilization' etc.</strong></strong></h4><p>See <a href="../17854/topics-6-16--1.html" title="New 2014 programme (First exams 2016) » Core & AHL » Incorporating IM, TOK, 'Utilization' etc. » Topics 6 & 16 ">separate page</a> which covers all of Topics 6 & 16</p><hr class="hidden"><h2>Practical work</h2><p><a href="../16637/iodination-of-propanone-1.html"><span style=""><b><span style="font-weight: normal;"><strong><img class="ico" src="../../../img/icons/lab-1.png"> </strong></span></b></span>Iodination of propanone </a></p></td></tr></tbody></table></div><hr class="hidden"><div class="greenBg"><h2 id="header-12">Teaching slides</h2><p>Teachers may wish to share these slides with students for learning or for reviewing key concepts.</p><div id="myCarousel-13" class="carousel slide" data-id="270"><!-- Carousel items --><div class="carousel-inner"><div class="active item"><a class="fancy" href="../../../tib-galleries/3-270/1611.png" rel="gallery-270" title=""><img alt="" src="files/tib-galleries/3-270/1611.png"></a><div class="carousel-caption"><p>Rate expression & reaction mechanism: </p></div></div><div class="item"><a class="fancy" href="../../../tib-galleries/3-270/1622.png" rel="gallery-270" title=""><img alt="" src="files/tib-galleries/3-270/1622.png"></a><div 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class="blueBg"><h2><span style="font-weight: bold;">Other resources</span></h2><p><strong>1. </strong>Deducing the rate expression by looking at initial rates by Richard Thornley, an IB teacher at the International school of Genoa. The video also looks at the units of the rate constant, <em>k, </em>although this is explained more in the next video.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/YLB732ij2oI?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/YLB732ij2oI">Rate expression <img src="http://www.thinkib.net/img/icons/video.png"></a></p><hr class="hidden"><p><strong>2. </strong>Another Richard Thornley video - this time on order or reaction and rate constants.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/9sMFJMuZzmg?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/9sMFJMuZzmg">Order of reaction <img src="http://www.thinkib.net/img/icons/video.png"></a></p><hr class="hidden"><p><strong>3</strong>. A nice visual demonstration by Richard Thornley showing the importance of the rate determining step.</p><p style="text-align: center;"><iframe allowfullscreen="" frameborder="0" height="280" src="//www.youtube.com/embed/swnJeRo-u8Q?rel=0" width="360"></iframe></p><p style="text-align: center;"><a href="http://youtu.be/swnJeRo-u8Q">Rate determining step <img class="ico" src="../../../img/icons/video-1.png"><span class="anchor" id="video-1" name="video-1"> </span></a></p><hr class="hidden"><p><strong>4. </strong>There are a lot of 'lecture' type video clips on YouTube on reaction mechanisms. 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I was searching around on the Internet and came across a worksheet with questions on the rate expression.The first two questions are1) Write the following for the reaction N2 + 3H2 → 2NH32) The rate constant for the...%0Ahttps%3A%2F%2Fwww.thinkib.net%2Fchemistry%2Fpage%2F17870%2Frate-expression-reaction-mechanism"><i class="fa fa-envelope"></i><span>Email</span></a></li></ul></li><li><a class="" href="chemistry/teaching-materials"><i class="fa fa-puzzle-piece colored"></i></a></li></ul></div></div><div style="border-top: solid 1px #eee;border-bottom: solid 1px #eee;padding: 4px 0 4px 0;line-height: 1em;color: #666;font-size: .8em"><small><em>All materials on this website are for the exclusive use of teachers and students at subscribing schools for the period of their subscription. 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